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732117

Pd-PEPPSI-IPent催化剂

≥95%, solid

别名:

[1,3-双(2,6-二-3-戊基苯基)咪唑-2-亚基](3-氯吡啶基)二氯化钯(II)

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250 mg
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$317.00
1 g
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$630.00
5 g
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$2,850.00
50 g
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$25,210.00

关于此项目

经验公式(希尔记法):
C40H56Cl3N3Pd
化学文摘社编号:
分子量:
791.67
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

$317.00


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产品名称

Pd-PEPPSI-IPent催化剂, ≥95%

Quality Segment

assay

≥95%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium

mp

195-201 °C

functional group

NHC

storage temp.

−20°C

SMILES string

Clc1cccnc1.CCC(CC)c2cccc(C(CC)CC)c2N3C=CN(c4c(cccc4C(CC)CC)C(CC)CC)\C3=[Pd](/Cl)Cl

InChI

1S/C35H52N2.C5H4ClN.2ClH.Pd/c1-9-26(10-2)30-19-17-20-31(27(11-3)12-4)34(30)36-23-24-37(25-36)35-32(28(13-5)14-6)21-18-22-33(35)29(15-7)16-8;6-5-2-1-3-7-4-5;;;/h17-24,26-29H,9-16H2,1-8H3;1-4H;2*1H;/q;;;;+2/p-2

InChI key

BCXSKTXOKALLAZ-UHFFFAOYSA-L

General description

Pd-PEPPSI-IPent催化剂是基于钯的催化剂,可用于催化交联反应中的C-N和C- C键形成。

Application

  • Stille偶联反应的催化剂 (eq.1)
  • Negishi偶联反应的催化剂 (eq.2)
  • Suzuki 偶联反应的催化剂(平衡3)
Reaction scheme for Pd catalyst PEPPSI<SUP>™</SUP>-IPent used in cross coupling reaction
对于小规模和高通量用途,产品为ChemBeads (928399

Legal Information

已获得专利,美国专利号7,250,510。由Total Synthesis Ltd独家授权销售。
PEPPSI is a trademark of Total Synthesis Ltd.

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此商品
928399669032725463
description

≥95%

description

-

description

98%, Umicore

description

Umicore

assay

≥95%

assay

~5 wt.% loading of catalyst

assay

98%

assay

-

reaction suitability

reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Cross Couplings, reaction type: Suzuki-Miyaura Coupling, reaction type: Heck Reaction, reagent type: catalyst
core: palladium, reaction type: Stille Coupling, reaction type: Sonogashira Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

reaction suitability

reaction type: Hiyama Coupling, core: palladium, reaction type: Cross Couplings, reagent type: catalyst, reaction type: Sonogashira Coupling, reaction type: Negishi Coupling, reaction type: Heck Reaction, reaction type: Stille Coupling, reagent type: catalyst
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Suzuki-Miyaura Coupling

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst, core: palladium, reaction type: Stille Coupling, reaction type: Negishi Coupling, reaction type: Cross Couplings, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Heck Reaction

form

solid

form

solid

form

-

form

solid

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

storage temp.

−20°C

storage temp.

-

storage temp.

-

storage temp.

2-8°C

mp

195-201 °C

mp

-

mp

230 °C

mp

331 °C


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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