75920

OXONE^® 四丁基铵盐

technical, ~1.6% active oxygen basis

• Synonym(s): 四丁基铵 OXONE^®, 四丁基铵过硫酸三聚盐
• CAS Number: 104548-30-3
• Beilstein: 5199887
• PubChem化学物质编号: 24886893
• NACRES: NA.22

Properties

• 等级: technical
• 质量水平: 100
• 测定: ~1.6% active oxygen basis
• 形式: powder
• reaction suitability: reagent type: oxidant
• mp: 144-146 °C
• SMILES string: OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-].CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC
• InChI: 1S/5C16H36N.2H2O5S.2H2O4S/c5*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*1-5-6(2,3)4;2*1-5(2,3)4/h5*5-16H2,1-4H3;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5
• InChI key: IGMBKNUVZFAHJM-UHFFFAOYSA-I

Description

应用

Reagent for:

• Oxidation of Hantzsch 1,4-Dihydropyridines catalyzed by manganese(III) Schiff Base complexes
• Epoxidation of alkenes
• Oxidation of sulfides and olefins
• Oxidation of alcohols
• Oxidation of aromatic amines for synthesis of azoxy arenes

其他说明

形成的 Oxone 特别适合于 CH₂Cl₂ 中敏感化合物的氧化反应；由醇和 THF 通过自由基偶联反应制备 2-四氢呋喃基醚的试剂

法律信息

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

Safety Information

• 象形图: GHS05,GHS07
• 警示用语：: Danger
• 危险声明: H302 - H314
• 预防措施声明: P260 - P280 - P301 + P312 + P330 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
• 危险分类: Acute Tox. 4 Oral - Skin Corr. 1B
• 储存分类代码: 8A - Combustible, corrosive hazardous materials
• WGK: WGK 3
• 闪点(F): Not applicable
• 闪点(C): Not applicable
• 个人防护装备: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges