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Merck

B65780

Sigma-Aldrich

(2-溴乙基)苯

98%

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别名:
2-苯乙基溴
线性分子式:
C6H5CH2CH2Br
CAS号:
分子量:
185.06
Beilstein:
507487
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

形狀

liquid

折射率

n20/D 1.556 (lit.)

bp

220-221 °C (lit.)

密度

1.355 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

BrCCc1ccccc1

InChI

1S/C8H9Br/c9-7-6-8-4-2-1-3-5-8/h1-5H,6-7H2

InChI 密鑰

WMPPDTMATNBGJN-UHFFFAOYSA-N

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應用

(2-溴乙基)苯可作为反应物合成:
  • 内酯衍生物,通过锡催化的双羰基化反应
  • α-亚氨基甲酰胺,通过芳基异腈和芳基异氰酸酯在Sml2参与下,使用一锅法三组分偶联反应合成。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2

水污染物質分類(WGK)

WGK 3

閃點(°F)

204.8 °F

閃點(°C)

96 °C

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Hisashi Masui et al.
Organic letters, 14(16), 4090-4093 (2012-08-07)
A one-pot, three-component coupling was accomplished via the nucleophilic addition of an alkylsamarium(III) species to isocyanides and the subsequent addition of the resultant imidoyl samarium(III) species to isocyanates under mild conditions for the formation of α-iminocarboxamides. The developed sequential C-C
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Science advances, 6(45) (2020-11-08)
Phenol is an important commodity chemical in the industry, which is currently produced using fossil feedstocks. Here, we report a strategy to produce phenol from lignin by directly deconstructing Csp2-Csp3 and C-O bonds under mild conditions. It was found that
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