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15512

Sigma-Aldrich

甲醛 溶液

meets analytical specification of USP, ≥34.5 wt. %

别名:
福尔马林
线性分子式:
HCHO
CAS号:
分子量:
30.03
Beilstein:
1209228
MDL编号:
eCl@ss:
39021101
PubChem化学物质编号:
NACRES:
NA.21

质量水平

200

蒸汽密度

1.03 (vs air)

蒸汽压

52 mmHg ( 37 °C)

测定

≥34.5 wt. %

自燃温度

572 °F

质量

meets analytical specification of USP

包含

9.0-15.0% methanol as stabilizer (GC)

浓度

25-50%

杂质

acidic reac. substances, complies
residual solvents, complies

灼烧残渣

≤0.01% (as SO4)

密度

1.09 g/mL at 25 °C (lit.)

适用性

corresponds for identity

SMILES string

[H]C([H])=O

InChI

1S/CH2O/c1-2/h1H2

InChI key

WSFSSNUMVMOOMR-UHFFFAOYSA-N

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一般描述

市场上销售的甲醛溶液是含有37%甲醛和8-10%甲醇的水溶液。通过加入催化量的镧系元素三氟甲磺酸酯,可以活化甲醛溶液。这种活化的甲醛溶液被用于与硅烯醇醚发生平稳的羟甲基化反应。甲醛溶液与硅烯醇醚反应,以高产率获得相应的羟甲基化加合物。

应用

甲醛溶液被用于制备甲醛储液,以便开发包容灵敏性和选择性试剂的透明溶胶凝胶,用于检测空气中甲醛。它可用于制备具有不同形状和不同粒径的纳米晶金属(Cu,Hg,Zn,Bi,Pb)硫化物。

其他说明

货号15512-4X2.5L-R的产品即将停产。请订购15512-2.5L-R单瓶装,因为其具体参数与上述产品本质相同。
货号15512-6X1L-R的产品即将停产。请订购15512-1L-R单瓶装,因为其具体参数与上述产品本质相同。

警示用语:

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 1 - STOT SE 3

靶器官

Respiratory system

Storage Class Code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK Germany

WGK 3

闪点(F)

143.6 °F

闪点(C)

62 °C

分析证书

原产地证书 (CofO)

Lanthanide Trifluoromethanesulfonates as Stable Lewis Acids in Aqueous Media. Yb (OTf)3 Catalyzed Hydroxymethylation Reaction of Silyl Enol Ethers with Commercial Formaldehyde Solution.
Kobayashi S.
Chemistry Letters (Jpn), 12, 2187-2190 (1991)
Microwave synthesis of nanocrystalline metal sulfides in formaldehyde solution.
Liao X-H, et al.
Materials Science and Engineering, B, 85(1), 85-89 (2001)
Lanthanide triflates as water-tolerant Lewis acids. Activation of commercial formaldehyde solution and use in the aldol reaction of silyl enol ethers with aldehydes in aqueous media.
Kobayashi S and Hachiya I.
The Journal of Organic Chemistry, 59(13), 3590-3596 (1994)
Opas Bunkoed et al.
Analytica chimica acta, 659(1-2), 251-257 (2010-01-28)
We report the development of transparent sol-gels with entrapped sensitive and selective reagents for the detection of formaldehyde. The sampling method is based on the adsorption of formaldehyde from the air and reaction with beta-diketones (for example acetylacetone) in a...
Cindy S Ma et al.
The Journal of experimental medicine, 205(7), 1551-1557 (2008-07-02)
Hyper-immunoglobulin E syndrome (HIES) is a primary immune deficiency characterized by abnormal and devastating susceptibility to a narrow spectrum of infections, most commonly Staphylococcus aureus and Candida albicans. Recent investigations have identified mutations in STAT3 in the majority of HIES...

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