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270970

吡啶

anhydrous, 99.8%

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关于此项目

经验公式(希尔记法):
C5H5N
化学文摘社编号:
分子量:
79.10
UNSPSC Code:
12352005
NACRES:
NA.21
PubChem Substance ID:
EC Number:
203-809-9
Beilstein/REAXYS Number:
103233
MDL number:
Assay:
99.8%
Grade:
anhydrous
Bp:
115 °C (lit.)
Vapor pressure:
10 mmHg ( 13.2 °C), 20 mmHg ( 25 °C)
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grade

anhydrous

Quality Segment

vapor density

2.72 (vs air)

vapor pressure

10 mmHg ( 13.2 °C), 20 mmHg ( 25 °C)

assay

99.8%

form

liquid

autoignition temp.

899 °F

expl. lim.

12.4 %

impurities

<0.003% water, <0.005% water (100 mL pkg)

evapn. residue

<0.0005%

color

colorless

refractive index

n20/D 1.509 (lit.)

pH

~8.81 (20 °C)

bp

115 °C (lit.)

mp

−42 °C (lit.)

density

0.978 g/mL at 25 °C (lit.)

SMILES string

C1=CN=CC=C1

InChI

1S/C5H5N/c1-2-4-6-5-3-1/h1-5H

InChI key

JUJWROOIHBZHMG-UHFFFAOYSA-N

General description

吡啶是一种碱性N-杂环化合物。它可充当氮供体配体并形成许多金属-吡啶复合物。其具有四面体和八面体几何形状的复合物可通过红外光谱研究来进行区分。

Application

吡啶可作为一种基质用于以下的转化:
  • 烷基三氯硅烷至三甲氧基烷基硅烷,而其可用作制备烷基硅酸盐的前体。
  • 1-茚满酮至1-茚满酮肟,而其可进行还原性环扩展以形成四氢喹啉。

它也可用于在不使用过渡金属催化剂的情况下催化卤代芳烃的硼酸化反应以形成芳基硼酸盐。
吡啶(py)可用于制备氧化钒纳米颗粒以及苯二甲酸铁,Fe(OH)(BDC)(py)0.85(BDC = 1,4-苯二甲酸酯,py =吡啶)。它可被用作Knoevenagel缩合反应中的催化剂。

Packaging


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此商品
33553P57506360570
Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

assay

99.8%

assay

≥99.5% (GC)

assay

≥99%

assay

≥99.0%

grade

anhydrous

grade

ACS reagent, puriss. p.a.

grade

-

grade

ACS reagent

form

liquid

form

liquid

form

liquid

form

liquid

expl. lim.

12.4 %

expl. lim.

12.4 %

expl. lim.

12.4 %

expl. lim.

12.4 %

refractive index

n20/D 1.509 (lit.)

refractive index

n20/D 1.509 (lit.)

refractive index

n20/D 1.509 (lit.)

refractive index

n20/D 1.509 (lit.)


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pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

存储类别

3 - Flammable liquids

flash_point_f

68.0 °F - closed cup

flash_point_c

20 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. Is this compound derived from plants?

    1 answer
    1. This product is typically synthetically manufactured and not plant-derived. However, the origin may vary on a lot-to-lot basis. More information may be found in the lot-specific Certificate of Origin. Please navigate to the ‘DOCUMENTATION’ section of the Product Detail Page to access a Certificate under the ‘Certificate of Origin’ tab:
      https://www.sigmaaldrich.com/product/sial/270970#product-documentation

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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