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Merck

70221

Supelco

甲酸铵

eluent additive for LC-MS, LiChropur, ≥99.0%

Ammonium formate

别名:

甲酸 铵盐

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$394.00
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$394.00


预计发货时间2025年11月03日详情


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关于此项目

线性分子式:
HCO2NH4
化学文摘社编号:
分子量:
63.06
Beilstein:
3625095
EC號碼:
MDL號碼:
分類程式碼代碼:
12352107
eCl@ss:
39021903
PubChem物質ID:
NACRES:
NB.21

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描述

anionic

品質等級

產品線

LiChropur

化驗

≥99.0% (calc. on dry substance, NT)
≥99.0%

形狀

crystals

品質

LiChropur

技術

LC/MS: suitable

雜質

insoluble matter, passes filter test
<2% water

燃燒殘留物(900 °C)

<0.1% (as SO4)

pH值

5.5-7.5 (25 °C, 1 M in H2O)

mp

119-121 °C (lit.)

溶解度

H2O: 1 M at 20 °C, clear, colorless

密度

1.26 g/mL at 25 °C (lit.)

負離子痕跡

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

正離子痕跡

Al: ≤1 mg/kg
As: ≤0.1 mg/kg
Ba: ≤1 mg/kg
Bi: ≤1 mg/kg
Ca: ≤5 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤1 mg/kg
K: ≤5 mg/kg
Li: ≤1 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Mo: ≤1 mg/kg
Na: ≤5 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Sr: ≤1 mg/kg
Zn: ≤1 mg/kg

&lambda ;

1 M in H2O

SMILES 字串

N.OC=O

紫外吸收

λ: 260 nm Amax: ≤0.01
λ: 280 nm Amax: ≤0.01

InChI

1S/CH2O2.H3N/c2-1-3;/h1H,(H,2,3);1H3

InChI 密鑰

VZTDIZULWFCMLS-UHFFFAOYSA-N

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156264798568516961
grade

eluent additive for LC-MS

grade

reagent grade

grade

anhydrous, reagent grade

grade

-

assay

≥99.0% (calc. on dry substance, NT)

assay

97%

assay

97%

assay

≥99.995% trace metals basis

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

form

crystals

form

granular, moist crystals

form

crystals

form

crystalline

pH

5.5-7.5 (25 °C, 1 M in H2O)

pH

5.5-7.5 (25 °C, 63.1 g/L)

pH

-

pH

-

solubility

H2O: 1 M at 20 °C, clear, colorless

solubility

-

solubility

-

solubility

-

一般說明

甲酸铵是甲酸的铵盐。它易于获得,性质稳定且无毒。它可以与碳载钯(Pd-C)或Raney-Nickel催化剂偶联使用。[1]

應用

在LC-MS/MS分析过程中,甲酸铵已被用作缓冲溶液用于筛选药物和外源性化合物。[2]它可被用作还原脂族和芳族硝基化合物的催化性氢转移剂。[1]
在LC-MS/MS分析过程中,甲酸铵已被用作缓冲溶液用于筛选药物和外源性化合物。它可用作还原脂肪族和芳香族硝基化合物的催化氢转移剂。
甲酸铵已用于通过毛细管电色谱法分离非甾体类抗炎药和寡糖混合物。这种成分还可用于通过HPLC和HPLC-MS方法分析磷脂酰丝氨酸、三酰基甘油和三酰基甘油氧化产物及低聚半乳糖醛酸。

法律資訊

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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François-Ludovic Sauvage et al.
Clinical chemistry, 52(9), 1735-1742 (2006-07-22)
In clinical and forensic toxicology, general unknown screening is used to detect and identify exogenous compounds. In this study, we aimed to develop a comprehensive general unknown screening method based on liquid chromatography coupled with a hybrid triple-quadrupole linear ion
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Evidence-based complementary and alternative medicine : eCAM, 2020, 4543761-4543761 (2020-12-22)
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A general procedure for mild and rapid reduction of aliphatic and aromatic nitro compounds using ammonium formate as a catalytic hydrogen transfer agent.
Ram, Siya, and Richard E. Ehrenkaufer.
Tetrahedron Letters, 25.32, 3415-3418 (1984)
Lin Wang et al.
Annals of palliative medicine, 10(4), 4354-4368 (2021-05-11)
To explore the role of intestinal flora in seborrhea, non-targeted metabolomics analysis was carried out. Fecal samples were collected from 5 seborrheic patients and 5 healthy controls from October 2019 to April 2020. Ultra-high performance liquid chromatography-quadrupole time-of-flight mass spectrometry
Nara Liessi et al.
JCI insight, 5(16) (2020-07-17)
In recent years, a number of drugs have been approved for the treatment of cystic fibrosis (CF). Among them, newly released Trikafta, a combination of 3 drugs (VX-661/VX-445/VX-770), holds great promise to radically improve the quality of life for a

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Chromatograms

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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