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  • C-C cross-coupling of primary and secondary benzylic alcohols using supported gold-based bimetallic catalysts.

C-C cross-coupling of primary and secondary benzylic alcohols using supported gold-based bimetallic catalysts.

ChemSusChem (2013-03-28)
Xiang Liu, Ran-Sheng Ding, Lin He, Yong-Mei Liu, Yong Cao, He-Yong He, Kang-Nian Fan
摘要

Clean alcohol-alcohol cross-coupling: A clean and efficient one-pot direct C-C cross-coupling of equimolar amounts of primary and secondary alcohols by a facile hydrogen autotransfer pathway is achieved over a robust and easily recovered hydrotalcite-supported Au-Pd bimetallic catalyst system. A variety of primary and secondary alcohols have been selectively converted into the corresponding β-alkylated ketones in good yields.

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