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  • Modelling uptake and toxicity of nickel in solution to Enchytraeus crypticus with biotic ligand model theory.

Modelling uptake and toxicity of nickel in solution to Enchytraeus crypticus with biotic ligand model theory.

Environmental pollution (Barking, Essex : 1987) (2014-02-18)
Erkai He, Hao Qiu, Cornelis A M Van Gestel
摘要

Protons and other cations may inhibit metal uptake and alleviate metal toxicity in aquatic organisms, but less is known about these interactions in soil organisms. The present study investigated the influence of solution chemistry on uptake and toxicity of Ni in Enchytraeus crypticus after 14 days exposure. Ca(2+), Mg(2+) and Na(+) were found to exert significant effects on both uptake and toxicity of Ni. An extended Langmuir model, which incorporated cation competition effects, well predicted Ni uptake. The LC50{Ni(2+)} predicted by a developed Biotic Ligand Model matched well with observed values. These suggest that cation competition needs to be taken into account when modelling uptake and effects. The binding constants of Ni(2+), Mg(2+) and Na(+) on the uptake and toxic action sites were similar, but for Ca(2+) they differed. This indicates that the effect of Ca(2+) on Ni(2+) toxicity cannot simply be explained by the competition for entry into organism.

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镍, foil, thickness 0.125 mm, ≥99.9%
Sigma-Aldrich
镍, foil, thickness 0.5 mm, 99.98% trace metals basis
Sigma-Aldrich
镍, wire, diam. 0.5 mm, ≥99.9% trace metals basis
Sigma-Aldrich
镍, foil, thickness 0.1 mm, 99.98% trace metals basis
Sigma-Aldrich
镍, wire, diam. 0.25 mm, ≥99.9%
Sigma-Aldrich
镍, rod, diam. 6.35 mm, ≥99.99% trace metals basis
Sigma-Aldrich
镍, wire, diam. 0.5 mm, ≥99.99% trace metals basis
镍, tube, 500mm, outside diameter 1.8mm, inside diameter 1.6mm, wall thickness 0.1mm, hard, 99.5%
镍, wire reel, 20m, diameter 0.025mm, as drawn, 99.98%
镍, wire reel, 1m, diameter 1.0mm, as drawn, 99%
镍, mesh, 100x250mm, nominal aperture 0.73mm, wire diameter 0.25mm, 26x26 wires/inch, open area 55%, plain weave mesh, 99%
镍, sphere, 100pcs, diameter 1.0mm, precision sphere grade 200, 99%
镍, foil, 50x50mm, thickness 0.30mm, as rolled, 99.98%
镍, wire reel, 5m, diameter 1.0mm, hard, 99.98%
镍, wire reel, 1m, diameter 0.75mm, as drawn, 99%
镍, rod, 100mm, diameter 12.7mm, 99.98%
镍, sphere, 200pcs, diameter 3.0mm, precision sphere grade 200, 99%
镍, foil, light tested, 100x100mm, thickness 0.015mm, 99.9%
镍, foil, 10mm disks, thickness 0.15mm, annealed, 99%
镍, foil, 4mm disks, thickness 0.075mm, annealed, 99%
镍, foil, 4mm disks, thickness 0.075mm, as rolled, 99.98%
镍, foil, 4mm disks, thickness 0.125mm, annealed, 99%
镍, foil, 4mm disks, thickness 0.125mm, annealed, 99.98%
镍, foil, 4mm disks, thickness 0.125mm, as rolled, 100%
镍, foil, 4mm disks, thickness 0.125mm, as rolled, 99.99+%
镍, foil, 4mm disks, thickness 0.15mm, annealed, 99%
镍, foil, 4mm disks, thickness 0.1mm, annealed, 99%
镍, foil, 4mm disks, thickness 0.20mm, annealed, 99%
镍, foil, 4mm disks, thickness 0.25mm, annealed, 99%
镍, foil, 4mm disks, thickness 0.25mm, annealed, 99.98%

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