Mechanisms in manganese catalysed oxidation of alkenes with H2O2.

Chemical Society reviews (2012-12-15)
Pattama Saisaha, Johannes W de Boer, Wesley R Browne
摘要

The development of new catalytic systems for cis-dihydroxylation and epoxidation of alkenes, based on atom economic and environmentally friendly concepts, is a major contemporary challenge. In recent years, several systems based on manganese catalysts using H(2)O(2) as the terminal oxidant have been developed. In this review, selected homogeneous manganese catalytic systems, including 'ligand free' and pyridyl amine ligand based systems, that have been applied to alkene oxidation will be discussed with a strong focus on the mechanistic studies that have been carried out.

材料
货号
品牌
产品描述

Sigma-Aldrich
锰, powder, ≥99.9% trace metals basis
Sigma-Aldrich
锰, powder, −325 mesh, ≥99% trace metals basis
Sigma-Aldrich
锰, chips, thickness <2.0 mm, 99%
锰, foil, 25x25mm, thickness 2mm, hot-pressed, 99.95%
锰, foil, 50x50mm, thickness 2mm, hot-pressed, 99.95%
锰, foil, not light tested, 100x100mm, thickness 0.0125mm, permanent polyester support, 98.7%
锰, foil, not light tested, 100x100mm, thickness 0.01mm, permanent polyester support, 98.7%
锰, foil, not light tested, 100x100mm, thickness 0.025mm, permanent polyester support, 98.7%
锰, foil, not light tested, 100x100mm, thickness 0.02mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.001mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.0025mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.002mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.003mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.004mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.005mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.006mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.007mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.008mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.009mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.0125mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.01mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.025mm, permanent polyester support, 98.7%
锰, foil, not light tested, 25x25mm, thickness 0.05mm, permanent polyester support, 98.7%
锰, foil, not light tested, 50x50mm, thickness 0.001mm, permanent polyester support, 98.7%
锰, foil, not light tested, 50x50mm, thickness 0.0025mm, permanent polyester support, 98.7%
锰, foil, not light tested, 50x50mm, thickness 0.003mm, permanent polyester support, 98.7%
锰, foil, not light tested, 50x50mm, thickness 0.004mm, permanent polyester support, 98.7%
锰, foil, not light tested, 50x50mm, thickness 0.005mm, permanent polyester support, 98.7%
锰, foil, not light tested, 50x50mm, thickness 0.006mm, permanent polyester support, 98.7%
锰, foil, not light tested, 50x50mm, thickness 0.007mm, permanent polyester support, 98.7%

社交媒体

LinkedIn icon
Twitter icon
Facebook Icon
Instagram Icon

Merck

科研、开发、生产。

作为生命科学行业的全球领先供应商,我们致力于为科研、生物技术开发和生产,以及制药药物疗法开发和生产提供各类解决方案和服务。

© 2021年版权归德国达姆施塔特默克集团(Merck KGaA)及/或其附属公司所有。版权所有。

未经许可,严禁复制本网站上的任何资料。