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134848

Triphenylmethanol

97%

Synonym(s):

Triphenylcarbinol, Trityl alcohol

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Pack SizeSKUAvailabilityPrice
50 g
Please contact Customer Service for Availability
€66.20
250 g
Please contact Customer Service for Availability
€199.00

About This Item

Linear Formula:
(C6H5)3COH
CAS Number:
Molecular Weight:
260.33
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-988-5
Beilstein/REAXYS Number:
1460837
MDL number:
Assay:
97%
Form:
solid

€66.20


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Quality Level

assay

97%

form

solid

bp

360 °C (lit.)

mp

160-163 °C (lit.)

solubility

dioxane: soluble 100 mg/mL, clear, colorless to faintly yellow

functional group

hydroxyl, phenyl

SMILES string

OC(c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C19H16O/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,20H

InChI key

LZTRCELOJRDYMQ-UHFFFAOYSA-N

General description

Triphenylmethanol forms 1:1 molecular complex with triphenylphosphine oxide[1]. It is a specific clathrate host for methanol and dimethyl sulphoxide and forms clathrate inclusion complexes. It undergoes reduction to triphenylmethane by 9, l0-dihydro-10-methylacridine in the presence of perchloric acid.

Application

Triphenylmethanol was used in the synthesis of of the two-electron reduction product of pyrylogen[2].

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This Item
8.21196Y00016541695343
assay

97%

assay

≥98.0% (HPLC)

assay

-

assay

-

Quality Level

200

Quality Level

200

Quality Level

-

Quality Level

-

solubility

dioxane: soluble 100 mg/mL, clear, colorless to faintly yellow

solubility

insoluble 1.43 g/L

solubility

-

solubility

-

bp

360 °C (lit.)

bp

-

bp

360 °C (lit.)

bp

360 °C (lit.)

form

solid

form

powder

form

-

form

-

mp

160-163 °C (lit.)

mp

160-163 °C (External MSDS)

mp

160-163 °C (lit.)

mp

160-163 °C (lit.)


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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Steiner
Acta crystallographica. Section C, Crystal structure communications, 56 (Pt 8), 1033-1034 (2000-08-16)
In the crystalline 1:1 molecular complex of triphenylmethanol (TPMeOH) and triphenylphosphine oxide (TPPO), C(19)H(16)O. C(18)H(15)OP, molecular dimers are formed which are linked by O-H. O=P hydrogen bonds. The dimers are aligned by sixfold phenyl embraces to form columns. The structure
Specific entrapment of methanol and dimethyl sulphoxide (DMSO) by a simple host compound (triphenylmethanol). Crystal structures of the Ph3COH? MeOH (1: 1) and Ph3COH? DMSO (2: 1) clathrate inclusion complexes.
Weber E, et al.
Journal of the Chemical Society. Chemical Communications, 17, 1195-1197 (1989)
Efficient Reduction of Triphenylmethanol to Triphenylmethane by 9, l0-Dihydro-10-methylacridine in the Presence of Perchloric Acid.
Ishikawa M, et al.
Chemical Society, Analytical Methods Committee, Analyst, 62, 3754-3756 (1989)



Global Trade Item Number

SKUGTIN
134848-250G04061838730336
134848-50G04061838730343

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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