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85429

Sinapic acid

suitable for matrix substance for MALDI-MS, ≥99.0% (T)

Sinapic acid
1 of 1 reviewers received a sample product or took part in a promotion

Synonym(s):

3,5-Dimethoxy-4-hydroxycinnamic acid, 4-Hydroxy-3,5-dimethoxy-cinnamic acid, Sinapinic acid

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About This Item

Empirical Formula (Hill Notation):
C11H12O5
CAS Number:
Molecular Weight:
224.21
UNSPSC Code:
23151817
NACRES:
NA.21
PubChem Substance ID:
EC Number:
208-487-3
Beilstein/REAXYS Number:
2699118
MDL number:
Assay:
≥99.0% (T)
Form:
powder
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Quality Level

assay

≥99.0% (T)

form

powder

analyte chemical class(es)

dendrimers, fullerenes, peptides, proteins

technique(s)

MALDI-MS: suitable

color

slightly yellow

mp

~202 °C

solubility

dioxane: 1 g/10 mL at Hot, clear to slightly hazy (Very Faint Yellow to Dark Yellow and Very Faint Orange to Dark Orange)

cation traces

Ba: ≤5 mg/kg, Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤20 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg

suitability

in accordance for UV test, suitable for matrix substance for MALDI-MS

SMILES string

COc1cc(\C=C\C(O)=O)cc(OC)c1O

InChI

1S/C11H12O5/c1-15-8-5-7(3-4-10(12)13)6-9(16-2)11(8)14/h3-6,14H,1-2H3,(H,12,13)/b4-3+

InChI key

PCMORTLOPMLEFB-ONEGZZNKSA-N

General description

Sinapic acid is a type of phenolic acid.[1] Removal of amino group from phenylalanine, catalysing with enzyme phenylalanine ammonia-lyase forms cinnamic acid. The precursor of hydroxycinnamates is produced after hydroxylation of benzene ring. One of the precursors produced is sinapic acid.

Application

Sinapic acid was suitable as phenolic standard for HPLC analysis in determination of Sinapic acid derivatives in Canola extracts.[1] 10 g/L of sinapinic acid with solvent was suitable as matrix for ultraviolet laser desorption mass spectrometric determination of proteins.[2] It was also suitable to use as matrix for MALDI-TOFMS and MALDI-ion mobility-TOFMS to determine phospholipids in tissue.[3]

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1 of 1

This Item
4950893878D7927
assay

≥99.0% (T)

assay

≥99.5% (HPLC)

assay

≥99.0% (HPLC)

assay

≥98%

solubility

dioxane: 1 g/10 mL at Hot, clear to slightly hazy (Very Faint Yellow to Dark Yellow and Very Faint Orange to Dark Orange)

solubility

dioxane: 1 g/10 mL at hot, clear, faintly yellow to yellow

solubility

-

solubility

H2O: slightly soluble (lit.)(lit.), methanol: water: soluble (lit.)(lit.), polar organic solvents: soluble (lit.)(lit.)

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

form

powder

form

-

form

-

form

powder

mp

~202 °C

mp

~202 °C

mp

195-205 °C (dec.)

mp

~202 °C

suitability

in accordance for UV test, suitable for matrix substance for MALDI-MS

suitability

in accordance for UV test, suitable for matrix substance for MALDI-MS

suitability

-

suitability

-


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pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Shelley N Jackson et al.
Journal of the American Society for Mass Spectrometry, 16(2), 133-138 (2005-02-08)
After water, lipids are the most common biomolecules found in the brain (12%). A brief perusal of the physiology, anatomy, and pathophysiology of the brain illustrates the importance of lipids. Recent advances in mass spectrometry have allowed the direct probing
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Journal of the American Oil Chemists' Society, 87(2), 147-155 (2010-02-17)
A high-performance liquid chromatographic (HPLC) method with diode array detection (DAD) was used to determine the total phenolics, including sinapic acid derivatives in canola. Ten Western Canadian canola seeds, six other commodity canola seeds, their corresponding press cakes and meals



Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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  1. Akron, Ohio
    • Reviews 2
    • Votes 0
    5 out of 5 stars.

    Excellent

    Arrived quickly, product was exactly as ordered and expected

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