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Gusev Group – Professor Product Portal

Dimitri Gusev

Professor Dimitri Gusev

Prof. Dmitry Gusev and his co-workers are developing organometallic compounds of transition metals with tridentate ('pincer'-type) ligands for applications in catalytic hydrogenation of compounds with polar C=O and C=N bonds, dehydrogenative coupling and dehydrogenation reactions of alcohols. These studies are supported by NMR spectroscopy and DFT calculations, and cover a wide range of important catalytic organic transformations, particularly reduction of esters, synthesis of amides and esters, and hydrogen production by acceptorless dehydrogenation of alcohols.

Gusev Group Website

Recent papers from the Gusev Group

1.
Spasyuk D, Smith S, Gusev DG. 2013. Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters. Angew. Chem. Int. Ed.. 52(9):2538-2542. http://dx.doi.org/10.1002/anie.201209218
2.
Spasyuk D, Smith S, Gusev DG. 2012. From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts. Angew. Chem. Int. Ed.. 51(11):2772-2775. http://dx.doi.org/10.1002/anie.201108956
3.
Gusev DG, Ozerov OV. 2011. Calculated Hydride and Fluoride Affinities of a Series of Carbenium and Silylium Cations in the Gas Phase and in C 6 H 5 Cl Solution. Chem. Eur. J.. 17(2):634-640. http://dx.doi.org/10.1002/chem.201000696
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DISCIPLINES

  • Organic Synthetic Chemistry
  • Catalysis

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