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135267

Sigma-Aldrich

Bromochloromethane

contains 100 ppm BHT as inhibitor, ≥99.5%

Linear Formula:
BrCH2Cl
CAS Number:
Molecular Weight:
129.38
Beilstein:
1730801
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

vapor density

4.5 (vs air)

vapor pressure

117 mmHg ( 20 °C)

assay

≥99.5%

may contain

100 ppm BHT as inhibitor

refractive index

n20/D 1.482 (lit.)

bp

68 °C (lit.)

mp

−88 °C (lit.)

density

1.991 g/mL at 25 °C (lit.)

SMILES string

ClCBr

InChI

1S/CH2BrCl/c2-1-3/h1H2

InChI key

JPOXNPPZZKNXOV-UHFFFAOYSA-N

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General description

Bromochloromethane is a by-product of disinfection of water by chlorination. It has potential antimethanogenic activity and reduces rumen methane production in dairy goats.

Application

Bromochloromethane was used in the synthesis and characterization of poly(methylene dicarboxylates).

Packaging

500 mL in glass bottle

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Dam. 1 - Ozone 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK Germany

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

W S Cuello et al.
Journal of toxicology, 2012, 629781-629781 (2012-06-22)
Bromochloromethane (BCM) is a volatile compound and a by-product of disinfection of water by chlorination. Physiologically based pharmacokinetic (PBPK) models are used in risk assessment applications. An updated PBPK model for BCM is generated and applied to hypotheses testing calibrated...
Synthesis and characterization of linear aliphatic poly (methylene dicarboxylate) s from caesium dicarboxylates and bromochloromethane.
Cimecioglu AL and East GC.
Makromol. Chem., 10(7), 319-324 (1989)
Leticia Abecia et al.
Frontiers in microbiology, 9, 2227-2227 (2018-10-26)
This work aimed to gain insight into the transition from milk to solid feeding at weaning combining genomics and metabolomics on rumen contents from goat kids treated with a methanogenic inhibitor (bromochloromethane, BCM). Sixteen goats giving birth to two kids...
Juan Li et al.
The Journal of chemical physics, 126(18), 184304-184304 (2007-05-19)
The pulsed field ionization-photoelectron (PFI-PE) spectrum of bromochloromethane (CH2BrCl) in the region of 85,320-88,200 cm-1 has been measured using vacuum ultraviolet laser. The vibrational structure resolved in the PFI-PE spectrum was assigned based on ab initio quantum chemical calculations and...
Gunjan Goel et al.
The British journal of nutrition, 101(10), 1484-1492 (2009-02-27)
Bromochloromethane (BCM), a halogenated methane analogue, was evaluated for its anti-methanogenic activity in both batch and continuous fermentation systems. For batch fermentation, a roughage-based substrate was incubated with mixed rumen microflora for 24 h at two concentrations of BCM (5...

Protocols

US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

US EPA Method 8260 describes the analysis of volatile organic compounds in solid wastes and ground waters. This application illustrates the analysis of many compounds commonly analyzed by this method using purge and trap coupled to GC-MS.

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