325252

Sigma-Aldrich

Titanium diisopropoxide bis(acetylacetonate)

75 wt. % in isopropanol

Synonym(s):
Ti(acac)2OiPr2, TYZOR AA organic titanate, Diisopropoxytitanium bis(acetylacetonate) solution
Linear Formula:
[(CH3)2CHO]2Ti(C5H7O2)2
CAS Number:
Molecular Weight:
364.26
MDL number:
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

Quality Level

form

solution

composition

Ti, 9-10.5% gravimetric

reaction suitability

core: titanium
reagent type: catalyst

concentration

75 wt. % in isopropanol

refractive index

n20/D 1.4935

density

0.995 g/mL at 25 °C

SMILES string

CC(C)O[Ti](OC(C)C)(O\C(C)=C\C(C)=O)O\C(C)=C\C(C)=O

InChI

1S/2C5H8O2.2C3H7O.Ti/c2*1-4(6)3-5(2)7;2*1-3(2)4;/h2*3,6H,1-2H3;2*3H,1-2H3;/q;;2*-1;+4/p-2/b2*4-3+;;;

Inchi Key

OVSGBKZKXUMMHS-VVDZMTNVSA-L

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Application

Titanium diisopropoxide bis (acetylacetonate) (TAA) may be used as a precursor to develop self assembled macroporous titania particles by evaporation. Commercial titanium(IV) bis(acetylacetonate) diisopropoxide was used to synthesize titanium acetylacetonate xerogels by drying, which could be further used to prepare titania films. TAA may be used as a hole blocking layer to fabricate solar cells.

Packaging

100, 500 mL in glass bottle

Legal Information

TYZOR is a registered trademark of E. I. du Pont de Nemours and Company

Signal Word

Danger

Hazard Statements

Target Organs

Central nervous system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN1219 - class 3 - PG 2 - Isopropanol, solution

WGK Germany

WGK 3

Flash Point(F)

53.6 °F - closed cup

Flash Point(C)

12 °C - closed cup

Titanium (IV) acetylacetonate xerogels for processing titania films: A thermoanalytical study.
Acik I, et al.
Journal of Thermal Analysis and Calorimetry, 97(1), 39-45 (2009)
Michael Kulbak et al.
The journal of physical chemistry letters, 6(13), 2452-2456 (2015-08-13)
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Fabrication of Porous Titania Particles from Water-in-Oil Emulsions for the Applications of Photocatalyst.
Cho YS, et al.
Journal of Dispersion Science and Technology, 37(5), 676-686 (2016)
Monovalent Cation Doping of CH3NH3PbI3 for Efficient Perovskite Solar Cells.
Abdi-Jalebi M, et al.
Journal of Visualized Experiments, 121, e55307-e55307 (2017)
Jingqi Liu et al.
Scientific reports, 9(1), 1362-1362 (2019-02-06)
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