341568

Sigma-Aldrich

Benzeneruthenium(II) chloride dimer

Synonym(s):
Benzeneruthenium dichloride dimer, Dibenzenetetrachlorodiruthenium, (Benzene)dichlororuthenium dimer, Bis(benzene)tetrachlorodiruthenium, Bis[(benzene)dichlororuthenium]
Linear Formula:
Ru2(C6H6)2Cl4
CAS Number:
Molecular Weight:
500.18
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

reaction suitability

core: ruthenium
reagent type: catalyst

SMILES string

Cl[Ru]Cl.Cl[Ru]Cl.c1ccccc1.c2ccccc2

InChI

1S/2C6H6.4ClH.2Ru/c2*1-2-4-6-5-3-1;;;;;;/h2*1-6H;4*1H;;/q;;;;;;2*+2/p-4

InChI key

YGXMUPKIEHNBNQ-UHFFFAOYSA-J

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Application

Hydrosilylation Catalysts

  • Catalyst for SNAr reactions of fluoroarenes and cyclic amines (eq. 1)
  • Precatalyst for the hydrogenation of β-keto esters (eq. 2)
  • Precursor for the preparation of other ruthenium catalysts (eq. 3)

Packaging

1, 5 g in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Articles
A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation.
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