343706

Sigma-Aldrich

Dichloro(p-cymene)ruthenium(II) dimer

greener alternative
Synonym(s):
Benzene, 1-methyl-4-(1-methylethyl)-, ruthenium complex, (p-Cymene)ruthenium(II) chloride dimer
Linear Formula:
[Ru(p-cymene)Cl2]2
CAS Number:
Molecular Weight:
612.39
MDL number:
PubChem Substance ID:
Pricing and availability is not currently available.

Quality Level

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: C-H Activation

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

mp

247.0-250.0 °C (dec.) (lit.)

SMILES string

Cl[Ru]Cl.Cl[Ru]Cl.CC(C)c1ccc(C)cc1.CC(C)c2ccc(C)cc2

InChI

1S/2C10H14.4ClH.2Ru/c2*1-8(2)10-6-4-9(3)5-7-10;;;;;;/h2*4-8H,1-3H3;4*1H;;/q;;;;;;2*+2/p-4

InChI key

LAXRNWSASWOFOT-UHFFFAOYSA-J

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation

Packaging

1, 5 g in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

RIDADR

NONH for all modes of transport

WGK Germany

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Carina Sollert et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(14), 5380-5386 (2015-02-18)
The Ru-catalysed C2-H arylation of indoles and pyrroles by using boronic acids under oxidative conditions is reported. This reaction can be applied to tryptophan derivatives and tolerates a wide range of functional groups on both coupling partners, including bromides and...
Bin Li et al.
Dalton transactions (Cambridge, England : 2003), 41(36), 10934-10937 (2012-08-15)
The reaction of [RuCl(2)(p-cymene)](2) with arylimines and 4 equiv. of KOAc in methanol at room temperature produces stable (N^C)-cyclometallated ruthenium(II) complexes via C-H bond activation/deprotonation. This method can be applied also to nitrogen-containing molecules: N-phenylpyrazole, 2-phenyl-2-oxazoline and benzo[h]quinoline. N-Phenyl-pyrazole, [RuCl(2)(p-cymene)](2)...
Articles
A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation.
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