449598

Sigma-Aldrich

Aluminum chloride

anhydrous, powder, 99.99% trace metals basis

Synonym(s):
Aluminum trichloride, Trichloroaluminum, Aluminium trichloride
Linear Formula:
AlCl3
CAS Number:
Molecular Weight:
133.34
EC Number:
MDL number:
eCl@ss:
38120507
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

Quality Level

grade

anhydrous

vapor pressure

1 mmHg ( 100 °C)

assay

99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: aluminum

mp

190 °C (lit.)

solubility

benzene: slightly soluble(lit.)

Featured Industry

Battery Manufacturing

SMILES string

Cl[Al](Cl)Cl

InChI

1S/Al.3ClH/h;3*1H/q+3;;;/p-3

InChI key

VSCWAEJMTAWNJL-UHFFFAOYSA-K

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General description

Aluminum chloride may be manufactured by chlorination of liquid aluminum in ceramic lined reaction vessels at 600-700oC.

Application

High strength steel screws were coated electrochemically by Al in an acidic ionic liquid composed of 1-ethyl -3- methylimidazolium chloride and AlCl3. AlCl3 was used to form Al-Cd alloy. Anhydrous alumunium chloride is a catalyst in organic chemistry especially for Friedel-Crafts reactions. It is also be used as a nucleation agent in the production of TiO2 pigment by the chloride process.

Packaging

5, 25 g in ampule

Features and Benefits

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl3 added to help facilitate crystallization.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Supp Hazards

EUH014

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 1726 8 / PGII

WGK Germany

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Al-Cd Alloy Formation by Aluminum Underpotential Deposition from AlCl3+NaCl Melts on Cadmium Substrate
Niko Jovicevic, et al.
Metall. Mater. Trans. B, 44(1), 106-114 (2013)
Challenges in the electrochemical coating of high-strength steel screws by aluminum in an acidic ionic liquid composed of 1-Ethyl-3-methylimidazolium chloride and AlCl3
Sherif Zein El Abedin and Endres F
Journal of Solid State Electrochemistry, 17(4), 1127-1132 (2013)
Diagnosis and management of hyperhidrosis.
R A Benson et al.
BMJ (Clinical research ed.), 347, f6800-f6800 (2013-11-28)
Bagineni Prasad et al.
Chemical communications (Cambridge, England), 48(84), 10434-10436 (2012-09-20)
A conceptually new and straightforward introduction of sulfonyl groups at the C-7 position of an indole ring has been achieved via AlCl(3) mediated unexpected regioselective sulfonyl group migration for N-alkyl/aryl/heteroarylsulfonyl indoles affording potential inhibitors of Mycobacterium tuberculosis H37Rv chorismate mutase.
Mengyun Zhu et al.
Organic letters, 16(7), 1856-1859 (2014-03-19)
An unprecedented AlCl3-promoted formal [2 + 3]-cycloaddition of 1,1-cyclopropanes with readily available N-benzylic sulfonamides has been developed. Experimental evidence supports an unusual mechanism wherein the donor-acceptor cyclopropane serves as a source of 2-styrylmalonate rather than the "classical" 1,3-dipole. A broad...
Articles
In the last two decades, a new method termed solid-state metathesis (SSM) has been developed to synthesize compounds that are often difficult to produce conventionally.
Read More

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