667412

Sigma-Aldrich

Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II) hexafluorophosphate

Synonym(s):
[RuCp*(MeCN)3]PF6
Empirical Formula (Hill Notation):
C16H24N3PRuF6
CAS Number:
Molecular Weight:
504.42
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

reaction suitability

core: ruthenium
reagent type: catalyst

storage temp.

2-8°C

SMILES string

[Ru+].CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F.CC1C(C)=C(C)C(C)=C1C

InChI

1S/C10H16.3C2H3N.F6P.Ru/c1-6-7(2)9(4)10(5)8(6)3;3*1-2-3;1-7(2,3,4,5)6;/h6H,1-5H3;3*1H3;;/q;;;;-1;+1

InChI key

IYEMDYLFXFMECZ-UHFFFAOYSA-N

Application

Reagent use as catalyst precursors for carbon-carbon or carbon-heteroatom bond forming reactions.
A versatile catalyst for hydrosilylation of alkynes providing α-vinylsilanes.

Packaging

250 mg in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Markovnikov alkyne hydrosilylation catalyzed by ruthenium complexes.
B M Trost et al.
Journal of the American Chemical Society, 123(50), 12726-12727 (2001-12-14)
Barry M Trost et al.
Journal of the American Chemical Society, 127(50), 17644-17655 (2005-12-15)
The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes. Terminal alkynes afford access to alpha-vinylsilane products with good regioselectivity. Deuterium labeling studies indicate a clean trans addition process is at work. The same complex...
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A Highly Efficient Hydrosilylation Catalyst, sigma-aldrich is pleased to offer [Cp*Ru(MeCN)3]PF6, as well as a number of other catalysts for hydrosilylation.
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