702854

Sigma-Aldrich

Copper(II) phthalocyanine

triple-sublimed grade, >99.95% trace metals basis

Synonym(s):
CuPc, Pigment Blue 15, Phthalocyanine blue
Empirical Formula (Hill Notation):
C32H16CuN8
CAS Number:
Molecular Weight:
576.07
Colour Index Number:
74160
Beilstein/REAXYS Number:
4121848
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

grade

triple-sublimed grade

assay

>99.95% trace metals basis

mp

350 °C

λmax

678 nm

fluorescence

λem 404 nm

Orbital energy

HOMO 5.2 eV 
LUMO 3.5 eV 

OLED Device Performance

ITO/CuPc/NPD/Alq3/C60/Mg:Ag

  • Color: green
  • Max. Luminance: 17200 Cd/m2

ITO/CuPc/NPD/Alq3/LiF/Al
  • Color: red
  • Max. Luminance: 2000 Cd/m2
  • Turn-On Voltage: 7.5 V

ITO/CuPc/NPD/CBP:Firpic (6%)/BAlq3/LiF/Al
  • Color: blue
  • Max. EQE: 4.5 %

OPV Device Performance

ITO/CuPc/PTCDA/In

  • Short-circuit current density (Jsc): 53.1 mA/cm2
  • Open-circuit voltage (Voc): 0.57 V
  • Fill Factor (FF): 0.61
  • Power Conversion Efficiency (PCE): 4.2 %

ITO/PEDOT:PSS/CuPc/C60/BCP/Al
  • Short-circuit current density (Jsc): 18.8 mA/cm2
  • Open-circuit voltage (Voc): 0.58 V
  • Fill Factor (FF): 0.52
  • Power Conversion Efficiency (PCE): 3.6 %

SMILES string

c1ccc2c(c1)C3=NC4=N@@H5C(=Nc6n7c(N=C8c9ccccc9C%10=N@@H8Cu57N3C2=N%10)c%11ccccc6%11)c%12ccccc4%12

InChI

1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

InChI key

XCJYREBRNVKWGJ-UHFFFAOYSA-N

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Related Categories

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Medhat A Shaibat et al.
The journal of physical chemistry. B, 114(13), 4400-4406 (2010-03-17)
Cu(II)(phthalocyanine) (CuPc) is broadly utilized as an archetypal molecular semiconductor and is the most widely used blue printing pigment. CuPc crystallizes in six different forms; the chemical and physical properties are substantially modulated by its molecular packing among these polymorphs....
Jia Liu et al.
Journal of the American Chemical Society, 133(51), 21010-21015 (2011-11-24)
The bottom-up fabrication of surface hierarchical nanostructures is of great importance for the development of molecular nanostructures for chiral molecular recognition and enantioselective catalysis. Herein, we report the construction of a series of 2D chiral hierarchical structures by trinary molecular...
A Mugarza et al.
Physical review letters, 105(11), 115702-115702 (2010-09-28)
We study the electronic mechanisms underlying the induction and propagation of chirality in achiral molecules deposited on surfaces. Combined scanning tunneling microscopy and ab initio electronic structure calculations of Cu-phthalocyanines adsorbed on Ag(100) reveal the formation of chiral molecular orbitals...
Masaya Hirade et al.
ACS applied materials & interfaces, 3(1), 80-83 (2011-01-05)
To enhance the performance of organic photovoltaic (OPV) cells, preparation of organic nanometer-sized pillar arrays is fascinating because a significantly large area of a donor/acceptor heterointerface having continuous conduction path to both anode and cathode electrodes can be realized. In...
Yu Li Huang et al.
Langmuir : the ACS journal of surfaces and colloids, 26(5), 3329-3334 (2010-02-24)
The self-assembly of the binary molecular system comprising copper(II) phthalocyanine (CuPc) and copper-hexadecafluoro-phthalocyanine (F(16)CuPc) on graphite has been investigated by in situ low-temperature scanning tunneling microscopy (LT-STM). The adsorption of this binary molecular system on graphite results in the formation...
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