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717282

Sigma-Aldrich

Chloro[tri(p-tolyl)phosphine]gold(I)

97%

Synonym(s):
Chloro[tri(4-methylphenyl)phosphine]gold(I)
Empirical Formula (Hill Notation):
C21H21AuClP
CAS Number:
Molecular Weight:
536.78
MDL number:
PubChem Substance ID:

assay

97%

form

powder

reaction suitability

core: gold
reagent type: catalyst

mp

205-210 °C

SMILES string

Cl[Au].Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc(C)cc3

InChI

1S/C21H21P.Au.ClH/c1-16-4-10-19(11-5-16)22(20-12-6-17(2)7-13-20)21-14-8-18(3)9-15-21;;/h4-15H,1-3H3;;1H/q;+1;/p-1

InChI key

QHHGSPBDJCGVPV-UHFFFAOYSA-M

Application

Reactant fro synthesis of:
  • Phosphine-gold(I) derivatives
  • Stable organogold(I) compound - catalyst for cyclization
  • Gold(I) acetylide complexes
  • Heterometallic gold(I)-rhenium(I) alkynyl complexes

Involved in reactions with unsaturated dimolybdenum anions

Reactant for oxidative addition of iodine to gold(I) complexes

Packaging

500 mg in glass bottle

Certificate of Analysis

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Certificate of Origin

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