730459

Sigma-Aldrich

(2S,2′S-(−)-N,N′-Bis(2-pyridylmethyl)-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate

greener alternative
Synonym(s):
Iron(II) (S,S-(2-({(S)-2-(S)-1-(pyridin-2-ylmethyl)pyrrolidin-2-ylpyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate, Fe(S,S-PDP), Fe(S,S-PDP)(CH3CN)2(SbF6)2, White Catalyst
Empirical Formula (Hill Notation):
C24H32F12FeN6Sb2
CAS Number:
Molecular Weight:
931.90
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

optical activity

α20/D −30.0 to −20.0°, c = 0.2 in acetonitrile

reaction suitability

core: iron
reagent type: catalyst
reaction type: C-H Activation

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

mp

>300 °C

SMILES string

Fe++.CC#N.CC#N.FSb-(F)(F)(F)(F)F.FSb-(F)(F)(F)(F)F.C1CC@H(C@H2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4

InChI

1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1

InChI key

XUNWHBGEOCZDBX-QSKJABRXSA-B

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Catalyst for:
  • Oxidative radical reactions
  • Selective oxidation of alkyl carbon-hydrogen bonds
  • Methylene group oxidation
Catalyst for greener ketone synthesis by selective C-H oxidation of methylenes.

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

Packaging

100, 500 mg in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Codes

Xi

Risk Statement

36/37/38

Safety Statement

26

RIDADR

NONH for all modes of transport

Certificate of Analysis
Certificate of Origin

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