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917745

Sigma-Aldrich

[Ni(dtbbpy)(H2O)4]Cl2

Empirical Formula (Hill Notation):
C18H32Cl2N2NiO4
CAS Number:
Molecular Weight:
470.06

form

powder

Quality Level

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

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[Ni(dtbbpy)(H2O)4]Cl2

Sigma-Aldrich

917745

[Ni(dtbbpy)(H2O)4]Cl2

[Ru(dtbbpy)3](PF6)2 ≥95%

Sigma-Aldrich

904953

[Ru(dtbbpy)3](PF6)2

form

powder

form

solid

form

powder

form

powder or crystals

mp

>300 °C

mp

149-156 °C (decomposition)

mp

-

mp

>300 °C

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

-

Application

[Ni(dtbbpy)(H2O)4]Cl2 is a Ni precatalyst used in a series of Ni/photoredox dual catalysis cross-coupling reactions. These transformations include the decarboxylative coupling of oxetanyl amino acids with aryl halides.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

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Certificate of Origin

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