B80100

Sigma-Aldrich

2-Bromopyridine

99%

Empirical Formula (Hill Notation):
C5H4BrN
CAS Number:
Molecular Weight:
158.00
Beilstein/REAXYS Number:
105789
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

99%

refractive index

n20/D 1.572 (lit.)

bp

192-194 °C (lit.)

density

1.657 g/mL at 25 °C (lit.)

SMILES string

Brc1ccccn1

InChI

1S/C5H4BrN/c6-5-3-1-2-4-7-5/h1-4H

InChI key

IMRWILPUOVGIMU-UHFFFAOYSA-N

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Application

2-Bromopyridine can be used as:
  • A building block in the formation of C−N bond by various cross coupling reactions.
  • A reactant in Negishi cross-coupling reaction with aryl halides catalyzed by palladium.
  • A reactant in the synthesis of 2′-pyridyldifluoroacetate with ethyl bromodifluoroacetate in presence of copper as a catalyst.

Packaging

25, 100, 500 g in glass bottle

Pictograms

Skull and crossbones

Signal Word

Danger

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 2810 6.1 / PGII

WGK Germany

WGK 3

Nicolas Großmann et al.
Dalton transactions (Cambridge, England : 2003), 45(45), 18365-18376 (2016-11-05)
Recently, research has revealed that molecules can be used to steer the local spin properties of ferromagnetic surfaces. One possibility to manipulate ferromagnetic-metal-molecule interfaces in a controlled way is to synthesize specific, non-magnetic molecules to obtain a desired interaction with...
Amino acid promoted CuI-catalyzed C-N bond formation between aryl halides and amines or N-containing heterocycles.
Zhang H, et al.
The Journal of Organic Chemistry, 70(13), 5164-5173 (2005)
A Versatile and Efficient Ligand for Copper-Catalyzed Formation of C-N, C-O, and P-C Bonds: Pyrrolidine-2-Phosphonic Acid Phenyl Monoester.
Rao H, et al.
Chemistry?A European Journal , 12(13), 3636-3646 (2006)
Long Xu et al.
Journal of lipid research, 61(4), 560-569 (2020-02-08)
This article focuses on the establishment of an accurate and sensitive quantitation method for the analysis of furan fatty acids. In particular, the sensitivity of GC/MS and UPLC/ESI/MS/MS was compared for the identification and quantification of furan fatty acids. Different...
Synthesis of solid 2-pyridylzinc reagents and their application in Negishi reactions.
Colombe JR, et al.
Organic Letters, 15(22), 5754-5757 (2013)

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