33589

Supelco

Clothianidin

PESTANAL®, analytical standard

Synonym(s):
(E)-1-(2-Chloro-5-thiazolylmethyl)-3-methyl-2-nitroguanidine
Empirical Formula (Hill Notation):
C6H8ClN5O2S
CAS Number:
Molecular Weight:
249.68
MDL number:
PubChem Substance ID:
NACRES:
NA.24
Pricing and availability is not currently available.

Quality Level

grade

analytical standard

product line

PESTANAL®

form

neat

CofA

certificate is enclosed in each package

shelf life

limited shelf life, expiry date on the label

application(s)

HPLC: suitable
gas chromatography (GC): suitable

Featured Industry

Agriculture
Environmental

format

neat

SMILES string

CN\C(NCc1cnc(Cl)s1)=N/N+(O-)=O

InChI

1S/C6H8ClN5O2S/c1-8-6(11-12(13)14)10-3-4-2-9-5(7)15-4/h2H,3H2,1H3,(H2,8,10,11)

InChI key

PGOOBECODWQEAB-UHFFFAOYSA-N

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Related Categories

General description

Clothianidin is a neonicotinoid insecticide with excellent systemic action for a wide variety of insect pests, that acts effectively on nicotinic acetylcholine receptors (nAChR).
Find more information here: Neonicotinoids

Application

Clothianidin may be used as a reference standard for the analysis of the analyte in agricultural samples using dual-labeled time-resolved fluoro-immunoassay (TRFIA), followed by gas chromatography (GC).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Sigma-Aldrich International GmbH

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Precautionary Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Hazard Codes

Xn,N

Risk Statement

22-50/53

Safety Statement

46-60-61

RIDADR

UN 3077 9 / PGIII

WGK Germany

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Antoine Abrieux et al.
PloS one, 11(11), e0167469-e0167469 (2016-12-03)
Neonicotinoid insecticides are widely used to protect plants against pest insects, and insecticide residues remaining in the environment affect both target and non-target organisms. Whereas low doses of neonicotinoids have been shown to disturb the behaviour of pollinating insects, recent...
Dual-labeled time-resolved fluoroimmunoassay for simultaneous detection of clothianidin and diniconazole in agricultural samples.
Sheng E, et al.
Food Chemistry, 192(2), 525-530 (2016)
Alin M Puinean et al.
PLoS genetics, 6(6), e1000999-e1000999 (2010-06-30)
The aphid Myzus persicae is a globally significant crop pest that has evolved high levels of resistance to almost all classes of insecticide. To date, the neonicotinoids, an economically important class of insecticides that target nicotinic acetylcholine receptors (nAChRs), have...
Zhengqun Zhang et al.
Scientific reports, 7(1), 8573-8573 (2017-08-19)
The mirid bug Apolygus lucorum (Meyer-Dür) has become a major pest in cotton fields and has led to significant yield losses due to the widespread use of transgenic Bt cotton in China. Eight neonicotinoid seed treatments were investigated to determine...
Chemistry of clothianidin and related compounds.
Uneme H.
Journal of Agricultural and Food Chemistry, 59(7), 2932-2937 (2010)
Articles
Determination of Neonicotinoids in Honey using a Chromolith RP-18 HPLC column and UV Detection
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Protocols
Extraction and Analysis of Neonicotinoid Pesticides from Flower Blossoms Using Supel<sup>™</sup> QuE and Ascentis<sup>®</sup> Express
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LC/MS/MS Analysis of Neonicotinoid Pesticides in Dandelion Blossoms on Ascentis® Express C18 after Dispersive SPE (QuEChERS) using Supel™ QuE
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Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.
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On Friday, April 27, 2018, the European Union decided to ban the use of three neonicotinoid insecticides from use on field crops, having deemed them dangerous to bees. This application demonstrates the analysis of these banned compounds and others from dandelion blossoms using QuEChERS and LC-MS.
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