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100242

3-Aminophenol

98%

Synonym(s):

m-Aminophenol

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5 g

Available to ship TODAYfromMILWAUKEE

$40.80
100 g

Available to ship TODAYfromMILWAUKEE

$54.20
500 g

Available to ship TODAYfromMILWAUKEE

$153.00
$114.75

About This Item

Linear Formula:
H2NC6H4OH
CAS Number:
Molecular Weight:
109.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-711-2
Beilstein/REAXYS Number:
636059
MDL number:
Assay:
98%
Form:
solid

$40.80


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Quality Level

assay

98%

form

solid

bp

164 °C/11 mmHg (lit.)

mp

120-124 °C (lit.)

storage temp.

room temp

SMILES string

Nc1cccc(O)c1

InChI

1S/C6H7NO/c7-5-2-1-3-6(8)4-5/h1-4,8H,7H2

InChI key

CWLKGDAVCFYWJK-UHFFFAOYSA-N

Application

3-Aminophenol has been used in the synthesis of disulfonated bis[4-(3-aminophenoxy)phenyl]sulfone (S-BAPS).
It can be used to synthesize:
  • Methyl 2-oxo-7-[(triphenylphosphoranylidene)amino]-2H-chromene-4-carboxylate by reacting with dimethyl acetylenedicarboxylate (DMAD) in the presence of triphenylphosphine.
  • 3-Amino-2-cyclohexen-1-one via palladium-catalyzed hydrogenation.


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This Item
2616458.00420410705
assay

98%

assay

98%

assay

-

assay

98%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

mp

120-124 °C (lit.)

mp

107-110 °C (lit.)

mp

122 °C

mp

-

bp

164 °C/11 mmHg (lit.)

bp

-

bp

164 °C/15 hPa

bp

-

form

solid

form

-

form

solid

form

powder

storage temp.

room temp

storage temp.

-

storage temp.

2-30°C

storage temp.

-


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Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 2

ppe

dust mask type N95 (US), Eyeshields, Gloves



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A Practical and One-Pot Procedure for the Synthesis of 3-Amino-2-cyclohexen-1-one from 3-Aminophenol.
Sajiki H
Organic Process Research & Development, 9(2), 219-220 (2005)
Sijing Chen et al.
Polymers, 11(6) (2019-06-20)
Benzoxazine containing fluorinated aromatic ether nitrile linkage (FAEN-Bz) had been synthesized from 2,6-dichlorobenzonitrile, 4,4'-(hexafluoroisopropylidene)diphenol (bisphenol AF), 3-Aminophenol, formaldehyde, phenol by condensation polymerization and Mannich ring-forming reaction. Structures of the monomer were verified by Proton NMR spectrum (1H-NMR) and Fourier transform
Vinyltriphenylphosphonium salt mediated synthesis of 1, 4-benzoxazine and coumarin derivatives.
Yavari I, et al.
Tetrahedron, 58(34), 6895-6899 (2002)



Global Trade Item Number

SKUGTIN
100242-5G04061838660756
100242-100G04061838660732
100242-500G04061838660749

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    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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