101990

Sigma-Aldrich

4,4′-Dibromooctafluorobiphenyl

99%

Linear Formula:
BrC6F4C6F4Br
CAS Number:
Molecular Weight:
455.92
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

99%

mp

113-115 °C (lit.)

SMILES string

Fc1c(F)c(c(F)c(F)c1Br)-c2c(F)c(F)c(Br)c(F)c2F

InChI

1S/C12Br2F8/c13-3-9(19)5(15)1(6(16)10(3)20)2-7(17)11(21)4(14)12(22)8(2)18

InChI key

YXLMNFVUNLCJJY-UHFFFAOYSA-N

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General description

4,4′-Dibromooctafluorobiphenyl undergoes lithiation with n-butyllithium to yield 4,4′-dilithiooctafluorobiphenyl and 4-lithio-4′-bromooctafluorobiphenyl.

Application

4,4′-Dibromooctafluorobiphenyl was used as internal standard to determine brominated flame retardants in sediment samples using on-line combination of pressurised hot water extraction and liquid chromatography-gas chromatography.

Packaging

1 g in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 3152PSN1 9 / PGII

WGK Germany

3

Certificate of Analysis

Certificate of Origin

Reactions and thermal decomposition of organolithium compounds derived from 4, 4'-dibromooctafluorobiphenyl.
Contigiani RA, et al.
Journal of Organometallic Chemistry, 32(1), 7-15 (1971)
Kati Kuosmanen et al.
Journal of chromatography. A, 943(1), 113-122 (2002-02-01)
Pressurised hot water extraction (PHWE) was coupled on-line with liquid chromatography-gas chromatography (LC-GC) to determine brominated flame retardants in sediment samples. After extraction with pressurised hot water the analytes were adsorbed in a solid-phase trap. The trap was dried with...
Yuanyuan Pei et al.
Marine pollution bulletin, 124(2), 1048-1054 (2016-11-09)
The occurrence of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyl (PCBs) in urban atmosphere in Guangzhou, China were assessed using homing pigeons as a biomonitor. Contaminant concentrations in lung were significantly higher than those in liver and fat, indicating chemical...
Huizhen Li et al.
Chemosphere, 144, 2427-2435 (2015-11-30)
Commercial mosquito repellents (MRs) are generally applied as mosquito coils, electric vaporizers (liquid and solid) or aerosol spray, with pyrethroids often being the active ingredients. Four types of MRs were applied individually in a 13-m(2) bedroom to study the occurrence...
Shunhui Wang et al.
Journal of hazardous materials, 393, 122420-122420 (2020-03-07)
Fipronil and its degradates have been detected ubiquitously in aquatic environment worldwide, yet little is known about its bioaccumulation potential. The goal of the present study was to measure bioconcentration factor (BCF) of sediment-associated fipronil in a benthic invertebrate, Lumbriculus...

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