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103284

2-Methoxy-5-methylaniline

99%

Synonym(s):

5-Methyl-o-anisidine, 6-Methoxy-m-toluidine, p-Cresidine

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About This Item

Linear Formula:
CH3OC6H3(CH3)NH2
CAS Number:
120-71-8
Molecular Weight:
137.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24846603
EC Number:
204-419-1
Beilstein/REAXYS Number:
637071
MDL number:
MFCD00007815
Assay:
99%
Form:
solid

Key Documents

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InChI key

WXWCDTXEKCVRRO-UHFFFAOYSA-N

InChI

1S/C8H11NO/c1-6-3-4-8(10-2)7(9)5-6/h3-5H,9H2,1-2H3

SMILES string

COc1ccc(C)cc1N

vapor density

4.7 (vs air)

assay

99%

form

solid

bp

235 °C (lit.)

Quality Level

200

mp

50-52 °C (lit.)

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1 of 4

This Item
630926M15001630934
2-Methoxy-5-methylaniline 99%

Sigma-Aldrich

103284

2-Methoxy-5-methylaniline

2-Methoxy-N-methylaniline 97%

Sigma-Aldrich

630926

2-Methoxy-N-methylaniline

4-Methoxy-2-methylaniline 98%

Sigma-Aldrich

M15001

4-Methoxy-2-methylaniline

3-Methoxy-N-methylaniline 97%

Sigma-Aldrich

630934

3-Methoxy-N-methylaniline

assay

99%

assay

97%

assay

98%

assay

97%

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

bp

235 °C (lit.)

bp

-

bp

248-249 °C (lit.)

bp

239-240 °C (lit.)

mp

50-52 °C (lit.)

mp

30-34 °C (lit.)

mp

13-14 °C (lit.)

mp

-

form

solid

form

-

form

liquid

form

-

vapor density

4.7 (vs air)

vapor density

-

vapor density

-

vapor density

-

General description

2-Methoxy-5-methylaniline is an aromatic amine present as contaminants in commercial hair dye samples[1].

Application

2-Methoxy-5-methylaniline was used in the synthesis of 4-(4-Amino-5-methoxy-2-methylphenylazo)-5-hydroxy-naphthalene-2,7-disulfonic acid[2]. 2-Methoxy-5-methylaniline was used to analyse the application of polymeric ionic liquids as selective solid-phase microextraction sorbent coatings for the analysis of genotoxic impurities and structurally alerting compounds such as alkyl halides and aromatics[3]. 2-Methoxy-5-methylaniline was used in a study to develop a sensitive analytical method for the determination of aromatic amines found in commercial hair dyes using high liquid chromatography coupled to an electrochemical detector by using the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide in the mobile phase[1].

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN4685
BCCJ3651
BCCH6274
BCCG2430
BCCG1767

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Kannan P Naicker et al.
Bioorganic & medicinal chemistry, 12(5), 1215-1220 (2004-02-26)
A structure-based design approach has been used to optimize a lead HIV-1 entry inhibitor targeted to the envelope glycoprotein gp41. The docking study on this lead compound revealed important structural requirements that need to be preserved as well as structural
Tien D Ho et al.
Journal of chromatography. A, 1240, 29-44 (2012-04-28)
A series of polymeric ionic liquids (PILs) possessing varied chemical makeup and composition were applied as selective solid-phase microextraction (SPME) sorbent coatings for the analysis of genotoxic impurities (GTIs) and related structurally alerting compounds, namely, alkyl halides and aromatics. In
p-Cresidine.
Report on carcinogens : carcinogen profiles, 10, 71-72 (2004-08-25)
J E Sagartz et al.
Toxicologic pathology, 26(4), 492-500 (1998-08-26)
The tumorigenic potential of phenobarbital was examined in a 26-wk carcinogenesis bioassay using p53 heterozygous mice and wild-type controls. Fifteen mice/sex/genotype were exposed to either 500 or 1,000 ppm phenobarbital in the diet. Dietary administration of 3,750 ppm p-cresidine, a
Y F Sasaki et al.
Mutation research, 412(2), 155-160 (1998-04-16)
We used a modification of the alkaline single-cell gel electrophoresis (SCG) (Comet) assay to evaluate the in vivo genotoxicity of two potent rodent bladder carcinogens, o-anisidine and p-cresidine, in mouse liver, lung, kidney, brain, and bone marrow, and in the
View All Related Papers

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