104876

Sigma-Aldrich

Trichlorovinylsilane

97%

Synonym(s):
Vinyltrichlorosilane, (Trichlorosilyl)ethylene
Linear Formula:
H2C=CHSiCl3
CAS Number:
Molecular Weight:
161.49
Beilstein/REAXYS Number:
1743440
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

Quality Level

vapor density

>1 (vs air)

vapor pressure

60 mmHg ( 23 °C)

assay

97%

refractive index

n20/D 1.436 (lit.)

bp

90 °C (lit.)

mp

−95 °C (lit.)

density

1.27 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

Cl[Si](Cl)(Cl)C=C

InChI

1S/C2H3Cl3Si/c1-2-6(3,4)5/h2H,1H2

InChI key

GQIUQDDJKHLHTB-UHFFFAOYSA-N

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Related Categories

General description

Trichlorovinylsilane may react with lithium-tert-butyl, and 1,3-enynes to yield isomeric silacyclobutanes and silacyclobutenes respectively.

Application

A study reports the possible use of this silane for treating Pluronic F127, chitosan for better attachment and proliferation of endothelial cells on biomaterials. Trichlorovinylsilane may be used to prepare epoxy terminated carbosiloxane.

Packaging

100, 500 g in glass bottle

Signal Word

Danger

Supp Hazards

EUH014 - EUH071

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN1305 - class 3 - PG 2 - Vinyltrichlorosilane, stabilized

WGK Germany

WGK 1

Flash Point(F)

50.0 °F - closed cup

Flash Point(C)

10 °C - closed cup

Micropatterning of proteins and mammalian cells on biomaterials.
Faseb Journal, 18(3), 525-527 (2004)
Xiangming Wu et al.
Colloids and surfaces. B, Biointerfaces, 130, 69-76 (2015-04-25)
Earlier work provided direction for development of responsive drug delivery systems based on modulation of the structure, amphiphilicity, and surface density of bioactive peptides entrapped within pendant polyethylene oxide (PEO) brush layers. In this work, we describe the sequential and...
Trichlorovinylsilane, lithium-tert-butyl, and 1, 3-enynes: A versatile combination for the competitive formation of silacyclobutanes and silacyclobutenes.
Canadian Journal of Chemistry, 78(11), 1445-1458 (2000)
John D DeSain et al.
Physical chemistry chemical physics : PCCP, 8(19), 2240-2248 (2006-05-12)
The absolute gas phase ultraviolet absorption spectra of trichlorovinylsilane and allyltrichlorosilane have been measured from 191 to 220 nm. Over this region the absorption spectra of both species are broad and relatively featureless, and their cross sections increase with decreasing...
Synthesis, characterization of an epoxy?terminated carbosiloxane and its application as a modifier in epoxy systems.
Polym. Eng. Sci., 52(4), 868-874 (2012)

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