According to literature, 1,1,1,3,3,3-Hexafluoro-2-propanol is soluble in 100% ethanol (to 10% v/v), which will yield colorless solution, chloroform, and water.
105228
1,1,1,3,3,3-Hexafluoro-2-propanol
≥99%
1,1,1,3,3,3-Hexafluoro-2-propanol
Synonym(s):
HFP, Hexafluoroisopropanol
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$87.50
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$168.00
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About This Item
Linear Formula:
(CF3)2CHOH
CAS Number:
Molecular Weight:
168.04
UNSPSC Code:
12352104
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-059-4
Beilstein/REAXYS Number:
1841007
MDL number:
Assay:
≥99%
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InChI key
BYEAHWXPCBROCE-UHFFFAOYSA-N
InChI
1S/C3H2F6O/c4-2(5,6)1(10)3(7,8)9/h1,10H
SMILES string
OC(C(F)(F)F)C(F)(F)F
assay
≥99%
refractive index
n20/D 1.275 (lit.)
bp
59 °C (lit.)
mp
−4 °C (lit.)
density
1.596 g/mL at 25 °C (lit.)
functional group
fluoro, hydroxyl
Quality Level
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General description
1,1,1,3,3,3-Hexafluoro-2-propanol is a solution-phase peptide chemistry solvent.[1] This fluorinated polar solvent of high ionizing power facilitates Friedel–Crafts-type reactions, using covalent reagents in the absence of a Lewis acid catalyst.[2] It also enhances the efficiency of rhodium(I)-catalyzed [4+2] intramolecular cycloaddition of ether-tethered alkynyl dienes and [5+2] cycloaddition of alkynyl vinylcyclopropanes.[3] 1,1,1,3,3,3-Hexafluoro-2-propanol clusters catalyzes the epoxidation of cyclooctene and 1-octene with hydrogen peroxide.[4]
Application
1,1,1,3,3,3-Hexafluoro-2-propanol was used for preparing hexafluoroalcohol-functionalized methacrylate polymers for lithographic/nanopatterning materials[5].
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Repr. 2 - Skin Corr. 1A - STOT RE 2 Oral
target_organs
Central nervous system
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
No data available
flash_point_c
No data available
ppe
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Hexafluoroalcohol-functionalized Methacrylate Monomers for Lithographic/Nanopatterning Materials.
Sanders DP, et al.
Material Matters, 6(1), 1-7 (2011)
Kinetic Studies of Olefin Epoxidation with Hydrogen Peroxide in 1, 1, 1, 3, 3, 3-Hexafluoro-2-propanol Reveal a Crucial Catalytic Role for Solvent Clusters.
Berkessel A and Adrio JA.
Advanced Synthesis & Catalysis, 346(2-3), 275-280 (2004)
Rita Sobreiro-Almeida et al.
Materials science & engineering. C, Materials for biological applications, 103, 109866-109866 (2019-07-28)
Kidney diseases are recognized as a major health problem, which affect 10% of the population. Because currently available therapies have many limitations, some tissue engineering strategies have been emerging as promising approaches in this field. In this work, porcine kidneys
Akio Saito et al.
The Journal of organic chemistry, 71(17), 6437-6443 (2006-08-12)
In fluorinated alcohols, the cationic Rh(I) species, which is derived from [Rh(COD)Cl]2 and AgSbF6, efficiently catalyzed intramolecular [4+2] cycloaddition reactions of ester-tethered 1,3-diene-8-yne derivatives. The catalytic system was also effective in intramolecular [5+2] cycloaddition reactions of ester-tethered omega-alkynyl vinylcyclopropane compounds.
Lewis acid catalyst free electrophilic alkylation of silicon-capped pi donors in 1,1,1,3,3,3-hexafluoro-2-propanol.
Maxim O Ratnikov et al.
Angewandte Chemie (International ed. in English), 47(50), 9739-9742 (2008-11-05)
Articles
To keep pace with Moore′s Law, there is a continuing need in the semiconductor industry to achieve higher circuit density in microelectronic devices.
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What is Product 105228, 1,1,1,3,3,3-Hexafluoro-2-propanol, soluble in?
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What is the Department of Transportation shipping information for this product?
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Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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What type of gloves should be worn while handling Product 105228, 1,1,1,3,3,3-Hexafluoro-2-propanol?
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We would recommend using neoprene gloves while handling this compound.
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How should Product 105228, 1,1,1,3,3,3-Hexafluoro-2-propanol, be stored?
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1,1,1,3,3,3-Hexafluoro-2-propanol should be stored in a cooler prior to opening since this product evaporates quickly and this will relieve pressure within the bottle.
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