109207

Sigma-Aldrich

2-Methyl-2-propanethiol

99%

Synonym(s):
tert-Butyl mercaptan, TBM
Linear Formula:
(CH3)3CSH
CAS Number:
Molecular Weight:
90.19
Beilstein/REAXYS Number:
505947
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

vapor density

3.1 (vs air)

vapor pressure

303.5 mmHg ( 37.7 °C)

assay

99%

refractive index

n20/D 1.423 (lit.)

bp

62-65 °C (lit.)

mp

-0.5 °C (lit.)

solubility

H2O: slightly soluble
alcohol: very soluble
diethyl ether: very soluble

density

0.8 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)S

InChI

1S/C4H10S/c1-4(2,3)5/h5H,1-3H3

InChI key

WMXCDAVJEZZYLT-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

2-Methyl-2-propanethiol undergoes ring opening nucleophilic reaction with 3-isothiazolones and reaction kinetics studies suggested reaction was second order in thiol and third order overall.

Application

2-Methyl-2-propanethiol was used in reaction of 2-methyl-2-propanethiol on Mo(110) using temperature programmed reaction, high resolution electron enegy loss and X-ray photoelectron spectroscopies. It was used in the synthesis of chain-transfer agents for reversible addition-fragmentation chain-transfer copolymerization of vinylidene chloride and methyl acrylate.

Packaging

100, 500 mL in Sure/Seal™
2 L in Sure/Seal™

Signal Word

Danger

Hazard Statements

Precautionary Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 2347 3 / PGII

WGK Germany

WGK 3

Flash Point(F)

-13.0 °F - closed cup

Flash Point(C)

< -25 °C - closed cup

Reversible addition-fragmentation chain-transfer (RAFT) copolymerization of vinylidene chloride and methyl acrylate.
Severac R, et al.
Polymer International, 51(10), 1117-1122 (2002)
Ursula K Rohlwink et al.
Nature communications, 10(1), 3767-3767 (2019-08-23)
Tuberculous meningitis (TBM) is the most severe form of TB with high rates of mortality and morbidity. Here we conduct RNA-sequencing on whole blood as well as on ventricular and lumbar cerebrospinal fluid (CSF) of pediatric patients treated for TBM....
Laura Seynaeve et al.
NeuroImage. Clinical, 21, 101657-101657 (2019-01-21)
Transcranial magnetic stimulation (TMS) is a useful technique to help localize motor function prior to neurosurgical procedures. Adequate modelling of the effect of TMS on the brain is a prerequisite to obtain reliable data. Twelve patients were included with perirolandic...
Koen Ameloot et al.
European heart journal, 40(22), 1804-1814 (2019-03-22)
During the first 6-12 h of intensive care unit (ICU) stay, post-cardiac arrest (CA) patients treated with a mean arterial pressure (MAP) 65 mmHg target experience a drop of the cerebral oxygenation that may cause additional cerebral damage. Therefore, we investigated whether...
Suzaan Marais et al.
The Journal of infectious diseases, 215(5), 677-686 (2016-12-10)
Tuberculous meningitis (TBM) is a frequent cause of meningitis in individuals with human immunodeficiency virus (HIV) infection, resulting in death in approximately 40% of affected patients. A severe complication of antiretroviral therapy (ART) in these patients is neurological tuberculosis-immune reconstitution...

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service

Social Media

LinkedIn icon
Twitter icon
Facebook Icon
Instagram Icon

MilliporeSigma

Research. Development. Production.

We are a leading supplier to the global Life Science industry with solutions and services for research, biotechnology development and production, and pharmaceutical drug therapy development and production.

© 2021 Merck KGaA, Darmstadt, Germany and/or its affiliates. All Rights Reserved.

Reproduction of any materials from the site is strictly forbidden without permission.