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111279

4-Penten-1-ol

99%

Synonym(s):

2-Allylethyl alcohol

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1 g

Available to ship TODAYfromMILWAUKEE

$59.40
10 g

Available to ship TODAYfromMILWAUKEE

$151.00
$113.25
50 g

Available to ship TODAYfromMILWAUKEE

$620.00
$465.00

About This Item

Linear Formula:
CH2=CH(CH2)3OH
CAS Number:
Molecular Weight:
86.13
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39020310
UNSPSC Code:
12352100
EC Number:
212-473-2
MDL number:
Beilstein/REAXYS Number:
1560163
Assay:
99%

$59.40


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Quality Level

assay

99%

refractive index

n20/D 1.429 (lit.)

bp

134-137 °C (lit.)

density

0.834 g/mL at 25 °C (lit.)

functional group

allyl, hydroxyl

SMILES string

OCCCC=C

InChI

1S/C5H10O/c1-2-3-4-5-6/h2,6H,1,3-5H2

InChI key

LQAVWYMTUMSFBE-UHFFFAOYSA-N

General description

4-penten-1-ol forms ester bond at the C terminus of the linear peptide in solution with HATU as coupling agent[1].

Application

4-Penten-1-ol can be used as a reactant to prepare sulfamate ester by reacting with chlorosulfonyl isocycanate (142662).The derived ester undergoes an enantioselective intramolecular azridination reaction in the presence of Cu catalyst. 4-Penten-1-ol can also be used to study the epoxidation of olefins with oxo-diperoxo tungstate(VI) complex as catalyst and bicarbonate as co-catalyst.

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This Item
268992493023302481
assay

99%

assay

≥98%

assay

98%

assay

97%

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100

bp

134-137 °C (lit.)

bp

126-127 °C (lit.)

bp

63-65 °C/100 mmHg (lit.)

bp

154-155 °C (lit.)

density

0.834 g/mL at 25 °C (lit.)

density

0.892 g/mL at 25 °C (lit.)

density

0.89 g/mL at 25 °C (lit.)

density

0.904 g/mL at 25 °C (lit.)

refractive index

n20/D 1.429 (lit.)

refractive index

n20/D 1.438 (lit.)

refractive index

n20/D 1.446 (lit.)

refractive index

n20/D 1.445 (lit.)

functional group

allyl, hydroxyl

functional group

hydroxyl

functional group

hydroxyl

functional group

hydroxyl


pictograms

Flame

signalword

Warning

hcodes

Hazard Classifications

Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

118.4 °F - closed cup

flash_point_c

48 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Enantioselective Intramolecular Copper-Catalyzed Aziridination of Sulfamates
Audrey Esteoule.et al.
Synthesis, 1251-1251 (2007)
Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(VI) complex as catalyst.
Maiti SK, et al.
New. J. Chem., 30(3), 479-489 (2006)
Marina D Rvovic et al.
Journal of molecular modeling, 17(6), 1251-1257 (2010-08-17)
The mechanism of phenylselenoetherification of pent-4-en-1-ol using some bases (pyridine, triethylamine, quinoline, 2,2'-bipyridine) as catalyst was examined through studies of kinetics of the cyclization, by UV-VIS spectrophotometry. It was demonstrated that the intramolecular cyclization is facilitated in the presence of



Global Trade Item Number

SKUGTIN
111279-1G04061837864704
111279-10G04061838698865
111279-50G04061838698872

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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