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MilliporeSigma

111929

Sigma-Aldrich

4-Chlorotoluene

98%

Synonym(s):

1-Chloro-4-methylbenzene, 1-Methyl-4-chlorobenzene, 4-Methyl-1-chlorobenzene, 4-Methylchlorobenzene, 4-Methylphenyl chloride, p-Chloromethylbenzene, p-Chlorotoluene, p-Methylchlorobenzene, p-Tolyl chloride

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$110.00

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100 G
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About This Item

Linear Formula:
CH3C6H4Cl
CAS Number:
Molecular Weight:
126.58
Beilstein/REAXYS Number:
1903635
EC Number:
MDL number:
UNSPSC Code:
12352100
eCl@ss:
39050207
PubChem Substance ID:
NACRES:
NA.22

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$110.00


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vapor density

4.38 (vs air)

vapor pressure

10 mmHg ( 45 °C)

assay

98%

form

liquid

impurities

≤2% 2-chlorotoluene

refractive index

n20/D 1.52 (lit.)

bp

162 °C (lit.)

mp

6-8 °C (lit.)

density

1.07 g/mL at 25 °C (lit.)

functional group

chloro

SMILES string

Cc1ccc(Cl)cc1

InChI

1S/C7H7Cl/c1-6-2-4-7(8)5-3-6/h2-5H,1H3

InChI key

NPDACUSDTOMAMK-UHFFFAOYSA-N

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This Item
138509111910424757
assay

98%

assay

98%

assay

99%

assay

98%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

liquid

form

liquid

form

liquid

form

solid

refractive index

n20/D 1.52 (lit.)

refractive index

n20/D 1.522 (lit.)

refractive index

n20/D 1.525 (lit.)

refractive index

-

density

1.07 g/mL at 25 °C (lit.)

density

1.072 g/mL at 25 °C (lit.)

density

1.083 g/mL at 25 °C (lit.)

density

-

bp

162 °C (lit.)

bp

160-162 °C (lit.)

bp

157-159 °C (lit.)

bp

-

General description

The reaction of 4-chlorotouleneand phenylboronic acid with Pd(OAc)2/L•2HX as the catalyst is the model reaction for determining the efficiencies of bisimidazolylidene (L) ligand precursors[1].

Application

The product was used for the preparation model gas of 4-chlorotoulene by passing synthesized air into liquid 4-chlorotoulene[2].

signalword

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Flam. Liq. 3 - Skin Sens. 1

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

123.8 °F - closed cup

flash_point_c

51 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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