12320

Sigma-Aldrich

p-Benzoquinone dioxime

technical, ≥90% (TLC)

Linear Formula:
C6H4(=NOH)2
CAS Number:
Molecular Weight:
138.12
Beilstein/REAXYS Number:
2043234
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

grade

technical

assay

≥90% (TLC)

mp

243 °C (dec.) (lit.)

solubility

dioxane: soluble 0.1 g/10 mL, clear

SMILES string

O\N=C1/C=C\C(C=C1)=N\O

InChI

1S/C6H6N2O2/c9-7-5-1-2-6(8-10)4-3-5/h1-4,9-10H/b7-5-,8-6+

InChI key

LNHURPJLTHSVMU-CGXWXWIYSA-N

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General description

The electrochemical behaviour of p-benzoquinone dioxime on modified Pt electrodes has been studied in aqueous HClO4 solutions by employing cyclic voltammetric and rotating-disc or ring-disc techniques.

Application

p-Benzoquinone dioxime was used in oxidative regeneration of a variety of carbonyl compounds from their oximes using superoxide ion generated in situ by the phase transfer reaction between potassium superoxide and 18-crown-6.

Packaging

250 g in poly bottle

Biochem/physiol Actions

p-Benzoquinone dioxime is sex-specific rat carcinogen inducing tumours of the urinary bladder in female rats and is a direct-acting mutagen in Salmonella typhimurium TA982.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Bacchetta Loretta et al.
Journal of food science and technology, 56(8), 3627-3634 (2019-08-16)
Opuntia ficus indica by-products can be exploited as sources of high-value components for applications in food and other industries. The aim of the present work is to elucidate and optimize the mucilage extraction process from cladodes. The effect of five...
Oxidative regeneration of carbonyl compounds from their oximes using in situ generated superoxide.
Singh KN, et al
Indian J. Chem. B, 45(11), 2552-2552 (2006)
C Westmoreland et al.
Environmental and molecular mutagenesis, 19(1), 71-76 (1992-01-01)
P-Benzoquinone dioxime (BQD) appears to be a sex-specific rat carcinogen inducing tumours of the urinary bladder in female rats. The present paper shows that BQD is a direct-acting mutagen in Salmonella typhimurium TA98, confirming published data. In contrast to this...
A reaction model for the ECECE mechanism: Reduction of p-benzoquinone dioxime on Pt/M (upd) modified electrodes in HClO4 solutions.
Kokkinidis G and Papanastasiou G.
J. Electroanal. Chem. Interfac. Electrochem., 257(1), 239-255 (1998)
para-Benzoquinone dioxime.
IARC monographs on the evaluation of the carcinogenic risk of chemicals to humans, 29, 185-191 (1982-05-01)

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