124036

1-Bromo-3-chlorobenzene

99%

• Linear Formula: BrC₆H₄Cl
• CAS Number: 108-37-2
• Molecular Weight: 191.45
• Beilstein/REAXYS Number: 1446353
• EC Number: 203-575-8
• MDL number: MFCD00000568
• eCl@ss: 39080308
• PubChem Substance ID: 24847592
• NACRES: NA.22

Properties

• Quality Level: 200
• assay: 99%
• refractive index: n20/D 1.576 (lit.)
• bp: 196 °C (lit.)
• density: 1.63 g/mL at 25 °C (lit.)
• SMILES string: Clc1cccc(Br)c1
• InChI: 1S/C6H4BrCl/c7-5-2-1-3-6(8)4-5/h1-4H
• InChI key: JRGGUPZKKTVKOV-UHFFFAOYSA-N

Description

General description

1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K₄[Fe(CN)₆] as cyanating source.

Packaging

25, 100 g in glass bottle

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315 - H319
• Precautionary Statements: P302 + P352 - P305 + P351 + P338
• Personal Protective Equipment: dust mask type N95 (US),Eyeshields,Gloves
• RIDADR: NONH for all modes of transport
• WGK Germany: WGK 3
• Flash Point(F): 176.0 °F - closed cup
• Flash Point(C): 80 °C - closed cup