124818

Sigma-Aldrich

Biphenyl-4,4′-disulfonyl chloride

97%

Linear Formula:
ClSO2C6H4C6H4SO2Cl
CAS Number:
Molecular Weight:
351.23
Beilstein/REAXYS Number:
2222668
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

97%

mp

205-208 °C (lit.)

SMILES string

ClS(=O)(=O)c1ccc(cc1)-c2ccc(cc2)S(Cl)(=O)=O

InChI

1S/C12H8Cl2O4S2/c13-19(15,16)11-5-1-9(2-6-11)10-3-7-12(8-4-10)20(14,17)18/h1-8H

InChI key

OTFAWEIFBPUXOH-UHFFFAOYSA-N

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General description

Biphenyl-4,4′-disulfonyl chloride reacts with cycloinulohexaose in pyridine to form capped cyclofructan, 6A,6C-di-O-(biphenyl-4,4′-disulfonyl)-cycloinulohexaose.

Application

Biphenyl-4,4′-disulfonyl chloride was used in the synthesis of 6A,6D-diamino-6A,6D-dideoxy-β-cyclodextrin.

Packaging

25 g in glass bottle

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

UN 3261 8 / PGII

WGK Germany

WGK 3

Capped cyclofructan. Preparation and structure determination of 6A, 6C-di-O-(biphenyl-4, 4'-disulfonyl)-cycloinulohexaose.
Atsumi M, et al.
Tetrahedron Letters, 35(31), 5661-5664 (1994)
N Schaschke et al.
Chemistry & biology, 8(4), 313-327 (2001-04-28)
Human beta-tryptase is a mast cell specific trypsin-like serine protease that is thought to play a key role in the pathogenesis of diverse allergic and inflammatory disorders like asthma and psoriasis. The recently resolved crystal structure revealed that the enzymatically...
Harold Cruz et al.
Chirality (2018-06-07)
Herein, we report the synthesis of C2 -symmetric sulfonamides as homogeneous and heterogeneous organocatalysts and their application in the enantioselective conjugate 1,4-Michael addition of carbonylic nucleophiles to β-nitrostyrene. Organocatalysts hydrogen bond to β-nitrostyrene and enamine in the transition state, mimicking...

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