The aim of this study was to discover new nitrilases with useful activities, especially towards dinitriles that are precursors of high-value cyano acids. Genes coding for putative nitrilases of different origins (fungal, plant, or bacterial) with moderate similarities to known...

η1-Allylpalladium complexes with a tridentate PNP ligand with different phosphino groups.

Bruno Crociani et al.

Dalton transactions (Cambridge, England : 2003), 41(40), 12490-12500 (2012-09-08)

The iminodiphosphine 2-(PPh(2))C(6)H(4)-1-CH=NC(6)H(4)-2-(PPh(2)) (P-N-P') is used for the preparation of the complexes [Pd(η(1)-CHR(1)-CH=CR(2)R(3))(P-N-P')]BF(4) [R(1) = R(2) = R(3) = H: (1); R(1) = R(2) = Ph, R(3) = H: (2); R(1) = R(3) = H, R(2) = Ph: (3); R(1)...

Ultrafast excited state dynamics of the perylene radical cation generated upon bimolecular photoinduced electron transfer reaction.

Stéphane Pagès et al.

The journal of physical chemistry. A, 110(24), 7547-7553 (2006-06-16)

The ultrafast ground state recovery (GSR) dynamics of the radical cation of perylene, Pe(*+), generated upon bimolecular photoinduced electron transfer in acetonitrile, has been investigated using pump-pump-probe spectroscopy. With 1,4-dicyanobenzene as electron acceptor, the free ion yield is substantial and...

Synthesis, structural characterization, and unusual field-effect behavior of organic transistor semiconductor oligomers: inferiority of oxadiazole compared with other electron-withdrawing subunits.

Taegweon Lee et al.

Journal of the American Chemical Society, 131(5), 1692-1705 (2009-01-17)

A new series of heterocyclic oligomers based on the 1,3,4-oxadiazole ring were synthesized. Other electron-deficient cores (fluorenone and fumaronitrile) were introduced to investigate the oligomers as n-channel materials. The physical properties, thin film morphologies, and field-effect transistor characteristics of the...

2H-Azirines from a concerted addition of alkylcarbenes to nitrile groups.

Wolfgang Knoll et al.

Organic letters, 12(10), 2366-2369 (2010-04-20)

Photolysis of aziadamantanes in the presence of fumaronitrile (FN) unexpectedly afforded conjugated 2H-azirines resulting from addition of the carbene to the CN triple bond. This represents the first example of a direct azirine formation starting from an alkylcarbene for which...

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