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131490

4-Methylpyridine

98%

Synonym(s):

4-Picoline, 4-Methylpyridine

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Pack SizeSKUAvailabilityPrice
25 mL

Available to ship TODAYfromMILWAUKEE

$37.60

About This Item

Empirical Formula (Hill Notation):
C6H7N
CAS Number:
Molecular Weight:
93.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-626-4
Beilstein/REAXYS Number:
104586
MDL number:
Assay:
98%
Form:
liquid

$37.60


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vapor density

3.2 (vs air)

Quality Level

vapor pressure

4 mmHg ( 20 °C)

assay

98%

form

liquid

autoignition temp.

1000 °F

refractive index

n20/D 1.504 (lit.)

bp

145 °C (lit.)

mp

2.4 °C (lit.)

density

0.957 g/mL at 25 °C (lit.)

SMILES string

Cc1ccncc1

InChI

1S/C6H7N/c1-6-2-4-7-5-3-6/h2-5H,1H3

InChI key

FKNQCJSGGFJEIZ-UHFFFAOYSA-N

General description

4-Methylpyridine is a neutral N-donor ligand[1].

4-picoline (4-Mepy) forms isostructural complexes with iron and cobalt phthalocyanines.

Application

4-Methylpyridine was used in the preparation of a 1,2-dihydropyridide derivative[2].

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2396158.07049112437
assay

98%

assay

99%

assay

≥98.0% (GC)

assay

98%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

bp

145 °C (lit.)

bp

145 °C (lit.)

bp

145 °C/1013 hPa

bp

168 °C (lit.)

mp

2.4 °C (lit.)

mp

2.4 °C (lit.)

mp

3 °C

mp

-

density

0.957 g/mL at 25 °C (lit.)

density

0.957 g/mL at 25 °C (lit.)

density

0.95 g/cm3 at 20 °C

density

0.942 g/mL at 25 °C (lit.)

form

liquid

form

-

form

liquid

form

-


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pictograms

FlameSkull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

102.2 °F - closed cup

flash_point_c

39 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Comparative study of beryllium, magnesium and zinc phthalocyanine complexes with 4-picoline
Kubiak R, et al.
Polyhedron, 26, 4179-4186 (2007)
Michael S Hill et al.
Dalton transactions (Cambridge, England : 2003), 40(46), 12500-12509 (2011-10-12)
Reactions of the β-diketiminato n-butyl magnesium complex, [HC{(Me)CN(2,6-(i)Pr(2)C(6)H(3))}(2)Mg(n)Bu], with a range of substituted pyridines and fused-ring quinolines in the presence of PhSiH(3) has been found to result in dearomatisation of the N-heterocyclic compounds. This reaction is proposed to occur through
Susan M Chemaly et al.
Inorganic chemistry, 52(2), 1077-1083 (2012-12-28)
Equilibrium constants (log K) for substitution of coordinated H(2)O in aquacyanocobyrinic acid heptamethyl ester (aquacyanocobester, ACCbs) and aquacyano-stable yellow cobyrinic acid hexamethyl ester (aquacyano-stable yellow cobester, ACSYCbs), in which oxidation of the C5 carbon of the corrin interrupts the normal



Global Trade Item Number

SKUGTIN
18-0260-5-500ML-J04061838096364
47115-U04061835515042
L0657-1L04061838173072
L0657-500ML04061838179234
131490-25ML04061838728418

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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