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132004

p-Toluenesulfonyl hydrazide

97%

Synonym(s):

p-Toluenesulfonhydrazide, p-Toluenesulfonic acid hydrazide, p-Toluenesulfonyl hydrazide, Tosylhydrazide

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$115.00

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$243.00

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About This Item

Linear Formula:
CH3C6H4SO2NHNH2
CAS Number:
Molecular Weight:
186.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-407-3
Beilstein/REAXYS Number:
610130
MDL number:
Assay:
97%
Form:
powder

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InChI key

ICGLPKIVTVWCFT-UHFFFAOYSA-N

InChI

1S/C7H10N2O2S/c1-6-2-4-7(5-3-6)12(10,11)9-8/h2-5,9H,8H2,1H3

SMILES string

Cc1ccc(cc1)S(=O)(=O)NN

assay

97%

form

powder

mp

103-108 °C (lit.)

functional group

hydrazine

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1 of 4

This Item
566802152536712728
assay

97%

assay

97%

assay

95%

assay

≥98.0% (HPLC), 98%

mp

103-108 °C (lit.)

mp

139-143 °C (lit.)

mp

-

mp

-

form

powder

form

solid

form

-

form

crystals

functional group

hydrazine

functional group

amine, hydrazide, phenyl

functional group

tosylate

functional group

sulfonamide

Application

p-Toluenesulfonyl hydrazide was used as a reagent for the preparation of tosylhydrazones.[1] It was used to prepare dipyrazolo[1,5-a:4′,3′-c]pyridines[2] and 1,2,3-selenadiazole derivatives[3].

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 2 - Self-react. D

Storage Class

5.2 - Organic peroxides and self-reacting hazardous materials

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Journal of the American Chemical Society, 114, 966-966 (1992)
Journal of the Chemical Society. Perkin Transactions 1, 945-945 (1993)
Mousa Al-Smadi et al.
Molecules (Basel, Switzerland), 13(11), 2740-2749 (2008-11-07)
The commercially available aromatic polyketones 1a-d were utilized for the synthesis of the multi-arm1,2,3-selenadiazole derivatives 3a-d. The preparation starts with the reaction between compounds 1a-d and p-toluenesulfonyl hydrazide to give the corresponding tosylhydrazones 2a-d. Subsequent reaction with selenium dioxide leads
Wolfgang Holzer et al.
Beilstein journal of organic chemistry, 8, 2223-2229 (2013-02-01)
The synthesis of dipyrazolo[1,5-a:4',3'-c]pyridines is described. Easily obtainable 5-alkynylpyrazole-4-carbaldehydes, p-toluenesulfonyl hydrazide, and an aldehyde or ketone containing an α-hydrogen atom were reacted in a silver triflate catalyzed multicomponent reaction affording new tricyclic compounds with a dipyrazolo[1,5-a:4',3'-c]pyridine core. Detailed NMR spectroscopic
Journal of the American Chemical Society, 115, 2473-2473 (1993)

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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