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132179

Sigma-Aldrich

2,4,6-Trimethylaniline

98%

Synonym(s):

Mesidine

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$48.70
100 ML
$54.40

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25 ML
$48.70
100 ML
$54.40

About This Item

Linear Formula:
(CH3)3C6H2NH2
CAS Number:
88-05-1
Molecular Weight:
135.21
Beilstein/REAXYS Number:
636559
EC Number:
201-794-3
MDL number:
MFCD00007740
UNSPSC Code:
12352100
PubChem Substance ID:
24847550
NACRES:
NA.22

$48.70

In StockDetails

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Quality Level

200

assay

98%

form

liquid

refractive index

n20/D 1.551 (lit.)

bp

108-110 °C/11 mmHg (lit.)
233 °C (lit.)

density

0.963 g/mL at 25 °C (lit.)

SMILES string

Cc1cc(C)c(N)c(C)c1

InChI

1S/C9H13N/c1-6-4-7(2)9(10)8(3)5-6/h4-5H,10H2,1-3H3

InChI key

KWVPRPSXBZNOHS-UHFFFAOYSA-N

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Application

  • Synthesis and crystal structures of N,2,4,6-tetra-methyl-anilinium tri-fluoro-methane-sulfonate and N-iso-propyl-idene-N,2,4,6-tetra-methyl-anilinium tri-fluoro-methane-sulfonate.: This study presents the synthesis and structural analysis of two compounds derived from 2,4,6-Trimethylaniline, contributing to understanding its role in organic synthesis and crystal engineering (Stewart et al., 2024).
  • Analysis of aromatic amines in human urine using comprehensive multi-dimensional gas chromatography-mass spectrometry (GCxGC-MS).: This paper explores advanced analytical techniques for detecting aromatic amines, including 2,4,6-Trimethylaniline, demonstrating its relevance in environmental and biological studies (Lorenzo-Parodi et al., 2024).
  • Efficient Rhodium-Catalyzed Multicomponent Reaction for the Synthesis of Novel Propargylamines.: This research highlights the use of 2,4,6-Trimethylaniline in developing new catalytic methods, showcasing its importance in pharmaceutical intermediate synthesis (Rubio-Pérez et al., 2015).

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

204.8 °F - closed cup

flash_point_c

96 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL6514
BCCK5353
BCCD5454
BCCJ7640
BCCD1218

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Salma Shirin et al.
Environmental science & technology, 45(24), 10369-10377 (2011-11-05)
Sulfonated anthracenedione dyes are medium priority organic compounds targeted for environmental assessment under the Government of Canada's Chemical Management Plan (CMP). Since organic compounds undergo transformations in environmental matrices, understanding these transformations is critical for a proper assessment of their
Ariadna Garza-Ortiz et al.
Inorganic chemistry, 47(15), 6964-6973 (2008-07-03)
The synthetic, spectroscopic, structural, and biological studies of a bis(arylimino)pyridine Ru(III) chloride compound containing the ligand, 2,6-bis(2,4,6-trimethylphenyliminomethyl)pyridine are reported. The bis(arylimino)pyridine ligand, with three donor nitrogen atoms, was synthesized by condensation of 2,6-pyridinedicarboxaldehyde with 2,4,6-trimethylaniline. The Ru(III) complex, with formula
S K Clark et al.
Molecular immunology, 20(12), 1379-1384 (1983-12-01)
Inhibition of the catalytic activity of horseradish peroxidase by rabbit antisera was measured using alternate enzyme substrates. The same general inhibition curve patterns were obtained regardless of the electron donor or hydroperoxide used. In all cases typical biphasic inhibition patterns
2,4,5- and 2,4,6-Trimethylaniline and their hydrochlorides.
IARC monographs on the evaluation of the carcinogenic risk of chemicals to humans, 27, 177-188 (1982-04-01)
L Alvarez-Rodríguez et al.
The Analyst, 122(5), 459-463 (1997-05-01)
The spectrophotometric determination of the carbamate pesticides carbaryl, bendiocarb, carbofuran, methiocarb, promecarb and propoxur is proposed. The pesticides are hydrolyzed in alkaline medium to 1-naphthol or phenolates, which are coupled with diazotized trimethylaniline (TMA) in a sodium dodecyl sulfate micellar
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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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