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132306

Zinc acetylacetonate hydrate

Synonym(s):

Bis(2,4-pentanedionato)zinc, Zn(acac)2

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100 G

$95.20

500 G

$325.55

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About This Item

Linear Formula:
Zn(C5H7O2)2 · xH2O
CAS Number:
Molecular Weight:
263.61 (anhydrous basis)
Beilstein/REAXYS Number:
4166200
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

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form

solid

Quality Level

composition

Zn, 23-26% EDTA titration

reaction suitability

reagent type: catalyst

mp

135-138 °C (lit.)

SMILES string

[H]O[H].CC(=O)\C=C(\C)O[Zn]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.H2O.Zn/c2*1-4(6)3-5(2)7;;/h2*3,6H,1-2H3;1H2;/q;;;+2/p-2/b2*4-3-;;

InChI key

KUJHAYOLESEVSA-SUKNRPLKSA-L

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1 of 4

This Item
4809911.08802245763
form

solid

form

solid

form

solid

form

solid

composition

Zn, 23-26% EDTA titration

composition

-

composition

-

composition

Mn, 21.0-23.0% EDTA titration

mp

135-138 °C (lit.)

mp

135-138 °C (lit.)

mp

237 °C

mp

248-250 °C (dec.) (lit.)

reaction suitability

reagent type: catalyst

reaction suitability

reagent type: catalyst

reaction suitability

-

reaction suitability

-

Quality Level

200

Quality Level

-

Quality Level

300

Quality Level

100

General description

Zinc acetylacetonate hydrate (Zn(acac)2) is a hydrated metal organic complex that is hygroscopic in nature. It is majorly used as a precursor for the synthesis of zinc based nano and microparticles.[1][2]

Application

Zn(acac)2 can be in the fabrication of zinc based films and coatings in chemical vapor deposition for optoelectronic applications.[3][4]

Features and Benefits

Novel MOCVD precursor for the preparation of high-crystallinity (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

pictograms

Exclamation markEnvironment

signalword

Warning

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Zinc acetylacetonate hydrate adducted with nitrogen donor ligands: Synthesis, spectroscopic characterization, and thermal analysis
Brahma S and Shivashankar SA
Journal of Molecular Structure, 1101, 41-49 (2015)
Efficiency enhancement of organic and thin-film silicon solar cells with photochemical upconversion
Schulze TF, et al.
The Journal of Physical Chemistry C, 116(43), 22794-22801 (2012)
The synthesis of zinc oxide nanoparticles from zinc acetylacetonate hydrate and 1-butanol or isobutanol
Ambrozic G, et al.
Journal of Colloid and Interface Science, 346(2), 317-323 (2010)
A facile route to inverted polymer solar cells using a precursor based zinc oxide electron transport layer
De Bruyn P, et al.
Organic Electronics, 11(8), 1419-1422 (2010)

Articles

Few Monolayer Atomic Layer Deposition (ALD) on Surfaces and Interfaces for Energy Applications

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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