If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
134821
Boron trifluoride-methanol solution
50% w/w in methanol
Synonym(s):
BF3 methanol, BF3MeOH, Boron Trifluoride - Methanol Complex, Boron fluoride methanol, Boron trifluoride methanol, Boron trifluoride-methanol complex, boron fluoride methanol, borontrifluoride methanol
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
50 mL | Available to ship TODAYfromMILWAUKEE | $123.00 $104.55 |
250 mL | Available to ship TODAYfromMILWAUKEE | $165.00 |
4 x 25 mL | Available to ship TODAYfromMILWAUKEE | $229.00 |
1 L | Available to ship TODAYfromMILWAUKEE | $461.00 $391.85 |
About This Item
$104.55
List Price$123.00Save 15%Available to ship TODAYDetails
vapor pressure
19.5 mmHg ( 20 °C)
Quality Segment
form
liquid
autoignition temp.
788 °F
reaction suitability
core: boron, reagent type: Lewis acid, reagent type: catalyst
concentration
49-53% ( by NaOH, titration), 50% w/w in methanol
technique(s)
gas chromatography (GC): suitable
bp
59 °C/4 mmHg
density
1.203 g/mL at 25 °C
functional group
hydroxyl
storage temp.
2-8°C
SMILES string
CO.FB(F)F
InChI
1S/CH4O.BF3/c1-2;2-1(3)4/h2H,1H3;
InChI key
JBXYCUKPDAAYAS-UHFFFAOYSA-N
Application
Packaging
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| description 50% w/w in methanol | description 14% in methanol | description 12.5-15.5% BF3 basis | description purified by redistillation, ≥46.5% BF3 basis |
| concentration 49-53% ( by NaOH, titration), 50% w/w in methanol | concentration 14% in methanol, 12-16% (titration by NaOH) | concentration 12.5-15.5% boron trifluoride | concentration ≥46.5% boron trifluoride |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 200 |
| form liquid | form liquid | form - | form liquid |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. - | storage temp. 2-8°C |
| bp 59 °C/4 mmHg | bp - | bp - | bp 126-129 °C (lit.) |
| density 1.203 g/mL at 25 °C | density 0.859 g/mL at 25 °C | density 0.859 g/mL at 25 °C | density 1.15 g/mL (lit.) |
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signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT RE 2 Inhalation - STOT SE 1 - STOT SE 3
target_organs
Eyes,Central nervous system, Kidney, Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
49.5 °F
flash_point_c
9.7 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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