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136131

Sigma-Aldrich

1,2-Dimethylimidazole

97%

Synonym(s):

1,2-Dimethyl-1H-imidazole, 1,2DMZ

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5 G
$36.50
100 G
$48.40
500 G
$200.00

About This Item

Empirical Formula (Hill Notation):
C5H8N2
CAS Number:
Molecular Weight:
96.13
EC Number:
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

$36.50


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vapor pressure

1 mmHg ( 20 °C)

Quality Level

assay

97%

form

solid

autoignition temp.

896 °F

bp

204 °C (lit.)

mp

37-39 °C (lit.)

density

1.084 g/mL at 25 °C (lit.)

SMILES string

Cc1nccn1C

InChI

1S/C5H8N2/c1-5-6-3-4-7(5)2/h3-4H,1-2H3

InChI key

GIWQSPITLQVMSG-UHFFFAOYSA-N

General description

1,2-Dimethylimidazole reacts with copper(II) tetraacetate to yield cis-bis(acetato)bis(1,2-dimethylimidazole) copper(II) complex[1]. It undergoes Menschutkin reaction with benzyl bromide to yield 3-benzyl-1,2-dimethylimidazolium bromide and kinetics of reaction was studied in various ionic liquids and molecular organic solvents[2].

Application

1,2-Dimethylimidazole was used in the synthesis of 1,2-dimethyl-3-n-butylimidazoliumchloride and 1,2-dimethyl-3-n-propylimidazolium chloride[3]. It was also used in the synthesis of 1-(2-methoxyethyl)-2,3-dimethylimidazolium chloride and hexafluorophosphate salts[4].

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

197.6 °F - closed cup

flash_point_c

92 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves


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The coordination environment of mitochondrial cytochromes b.
K R Carter et al.
FEBS letters, 132(2), 243-246 (1981-09-28)
Wesley A Henderson et al.
Chemical communications (Cambridge, England), (35)(35), 3708-3710 (2006-10-19)
The crystal structures and thermal behavior of the 1-(2-methoxyethyl)-2,3-dimethylimidazolium chloride and hexa-fluorophosphate salts are compared with the analogous 1-butyl-2,3-dimethylimidazolium salts to examine the influence of the ether oxygen on salt thermal properties for a typical constituent cation used in the
Physical properties of substituted imidazolium based ionic liquids gel electrolytes.
Sutto TE, et al.
Zeitschrift fur Naturforschung, A, 57(11), 839-846 (2002)
Peng Lu et al.
Dalton transactions (Cambridge, England : 2003), 48(48), 17752-17762 (2019-11-26)
A short imidazolium based dication, with only three methylene units in the spacer linker, selectively directs the crystallization of zeolite HPM-12 (*UOE) as long as there is enough germanium present in the synthesis gel. The integrity of the dication is
Zhiming Zhou et al.
Analytica chimica acta, 678(2), 208-214 (2010-10-05)
Four novel ILs functionalized β-cyclodextrins (β-CDs) were prepared by treating 6-tosyl-β-cyclodextrin with 1,2-dimethylimidazole or 1-amino-1,2,3-triazole, and bonded to silica gel to obtain chiral stationary phases (CSPs) to be used in high-performance liquid chromatography (HPLC). The separation performances of these CSPs

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