138029

Sigma-Aldrich

Furil

98%

Empirical Formula (Hill Notation):
C10H6O4
CAS Number:
Molecular Weight:
190.15
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

98%

mp

163-165 °C (lit.)

SMILES string

O=C(C(=O)c1ccco1)c2ccco2

InChI

1S/C10H6O4/c11-9(7-3-1-5-13-7)10(12)8-4-2-6-14-8/h1-6H

InChI key

SXPUVBFQXJHYNS-UHFFFAOYSA-N

Gene Information

human ... ACHE(43), BCHE(590), CES1(1066)

General description

Furil undergoes catalytic asymmetric transfer hydrogenation to yield hydrofuroin.

Application

Furil was used in preparation of dioxomolybdenum(VI) complexes in situ.

Packaging

1 g in glass bottle

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Anzhelika Kabro et al.
Organic letters, 14(15), 4014-4017 (2012-07-27)
Catalytic asymmetric transfer hydrogenation of rac-furoin and furil produces hydrofuroin with up to 99% ee and 9:1 dr. This reaction provides an exceptionally easy access to optically active hydrofuroins in two straightforward steps from biomass-derived furfural (global production 200,000-300,000 t...
Syntheses and spectroscopic studies on macrocyclic complexes of dioxomolybdenum (VI) with furil as precursor.
Rao DP, et al.
E-Journal of Chemistry, 9(2), 497-503 (2012)

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