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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
140732
N,N-Dimethylformamide dimethyl acetal
technical grade, 94%
Synonym(s):
1,1-Dimethoxy-N,N-dimethylmethylamine, 1,1-Dimethoxytrimethylamine
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About This Item
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InChI key
ZSXGLVDWWRXATF-UHFFFAOYSA-N
InChI
1S/C5H13NO2/c1-6(2)5(7-3)8-4/h5H,1-4H3
SMILES string
COC(OC)N(C)C
grade
technical grade
assay
94%
form
liquid
reaction suitability
reaction type: C-C Bond Formation
Quality Level
refractive index
n20/D 1.396 (lit.)
bp
102-103 °C/720 mmHg (lit.)
density
0.897 g/mL at 25 °C (lit.)
functional group
amine, ether
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Related Categories
1 of 4
This Item | |||
|---|---|---|---|
| assay 94% | assay 95% | assay 95% | assay ≥95.0% (GC) |
| reaction suitability reaction type: C-C Bond Formation | reaction suitability - | reaction suitability - | reaction suitability - |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| bp 102-103 °C/720 mmHg (lit.) | bp 130-133 °C (lit.) | bp 79-80 °C/60 mmHg (lit.) | bp 130-133 °C (lit.) |
| density 0.897 g/mL at 25 °C (lit.) | density 0.859 g/mL at 25 °C (lit.) | density 0.838 g/mL at 25 °C (lit.) | density 0.859 g/mL at 25 °C (lit.) |
| refractive index n20/D 1.396 (lit.) | refractive index n20/D 1.400 (lit.) | refractive index n20/D 1.401 (lit.) | refractive index n20/D 1.397-1.401, n20/D 1.400 (lit.) |
Application
- An organocatalyst for the synthesis of 1,2-disubstituted-3,4-dihydronaphthalenes by the reaction of vinylarenes and electron-deficient alkynes.[1]
- A building block for the preparation of heterocyclic compounds such as enamines and amidines via formylation of methylene and amino groups.[2]
- A reagent in the synthesis of 1,4-diaryl-piperazine-2,5-diones by reacting with chloroacetamides.[3]
- A reagent along with enamine and alkyne for the preparation of 2,3,4,5-tetrasubstituted pyridine derivatives by three-component coupling reaction in the presence of Me3SiCl.[4]
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Sens. 1
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
42.8 °F
flash_point_c
6 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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