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MilliporeSigma

154261

Sigma-Aldrich

4-Bromo-3-methylaniline

97%

Synonym(s):

4-Bromo-m-toluidine

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10 G
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About This Item

Linear Formula:
BrC6H3(CH3)NH2
CAS Number:
Molecular Weight:
186.05
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

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Quality Level

assay

97%

form

solid

bp

240 °C (lit.)

mp

80-82 °C (lit.)

functional group

bromo

SMILES string

Cc1cc(N)ccc1Br

InChI

1S/C7H8BrN/c1-5-4-6(9)2-3-7(5)8/h2-4H,9H2,1H3

InChI key

MMEGELSFOYDPQW-UHFFFAOYSA-N

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This Item
154253115851261661
assay

97%

assay

97%

assay

98%

assay

95%

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100

bp

240 °C (lit.)

bp

240 °C (lit.)

bp

206 °C (lit.)

bp

-

form

solid

form

-

form

-

form

powder

mp

80-82 °C (lit.)

mp

57-59 °C (lit.)

mp

−10 °C (lit.)

mp

110-111 °C (lit.)

functional group

bromo

functional group

bromo

functional group

bromo

functional group

nitro

Application

4-Bromo-3-methylaniline was used in the preparation of 1-(4-bromo-3-methylphenyl)pyrrolidin-2-one[1].

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Multikilogram-scale synthesis of a biphenyl carboxylic acid derivative using a Pd/C-mediated suzuki coupling approach.
Organic Process Research & Development, 3(4), 248-252 (1999)

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