157457

Sigma-Aldrich

3,5-Di-tert-butyl-o-benzoquinone

98%

Linear Formula:
(CH3)3C2C6H2(=O)2
CAS Number:
Molecular Weight:
220.31
Beilstein/REAXYS Number:
2047944
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

assay

98%

mp

112-114 °C (lit.)

SMILES string

CC(C)(C)C1=CC(=O)C(=O)C(=C1)C(C)(C)C

InChI

1S/C14H20O2/c1-13(2,3)9-7-10(14(4,5)6)12(16)11(15)8-9/h7-8H,1-6H3

InChI key

NOUZOVBGCDDMSX-UHFFFAOYSA-N

Gene Information

human ... ACHE(43), BCHE(590), CES1(1066)

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General description

Reactions of the phosphinidene-bridged complexes Fe25-C5H5)2(μ-PR)(μ-CO)(CO)2 (R = Cy, Ph) with 3,5-di-tert-butyl-o-benzoquinone has been reported.

Application

3,5-Di-tert-butyl-o-benzoquinone was used in the preparation of benzoxazoles derivative ligands. It was also used in the preparation of 1,4-benzodioxines via hetero Diels Alder reaction with acyclic dienes.

Packaging

10 g in glass bottle

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Chinmoy Das et al.
Dalton transactions (Cambridge, England : 2003), 46(5), 1439-1448 (2017-01-11)
The reaction of anhydrous MCl
Determination of natural thiols by liquid chromatography after derivatization with 3,5-di-tert.-butyl-1,2-benzoquinone.
Y Imai et al.
Journal of chromatography, 420(2), 404-410 (1987-09-25)
Adám Kupán et al.
Journal of inorganic biochemistry, 103(3), 389-395 (2009-01-13)
The attempted alkylation of 1,3-bis(2'-pyridylimino)isoindoline (indH) by the use of n-BuLi and subsequent alkyl halides led to quaternization of the pyridine nitrogens and the zwitterionic monodentate N-ligand (Me(2)ind)I was formed. By the use of the ligand the copper(I) complex [Cu(I)(Me(2)ind)I(2)]...
Laura Gasque et al.
Journal of inorganic biochemistry, 102(5-6), 1227-1235 (2008-02-23)
The crystal structure and magnetic properties of a dinuclear copper(II) complex of the ligand [2,8-dimethyl-5,11-di-(dimethylethyleneamine) 1,4,5,6,7,10,11,12-octahydroimidazo [4,5-h] imidazo [4,5-c] [1,6]diazecine] dimeim have been investigated. Also, its catecholase activity has been explored in different solvent mixtures: MeCN/H2O and OH/H2O, each at...
Hetero Diels-Alder reactions of 3, 5-di-tert-butyl-o-benzoquinone with acyclic dienes: novel synthesis of 1, 4-benzodioxines.
Nair V and Kumar S.
Journal of the Chemical Society. Chemical Communications, 11, 1341-1342 (1994)

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