157716

2,6-Diisopropylaniline

technical grade, 90%

• Synonym(s): 2,6-Bis(1-methylethyl)benzenamine, 2,6-Bis(propan-2-yl)aniline, 2,6-Diisopropylphenylamine
• Linear Formula: [(CH₃)₂CH]₂C₆H₃NH₂
• CAS Number: 24544-04-5
• Molecular Weight: 177.29
• Beilstein/REAXYS Number: 2208763
• EC Number: 246-305-4
• MDL number: MFCD00008887
• UNSPSC Code: 12352100
• PubChem Substance ID: 24849695
• NACRES: NA.22

Properties

• grade: technical grade
• Quality Level: 100
• vapor pressure: <0.01 mmHg ( 20 °C)
• assay: 90%
• form: liquid
• refractive index: n20/D 1.532 (lit.)
• bp: 257 °C (lit.)
• mp: −45 °C (lit.)
• density: 0.94 g/mL at 25 °C (lit.)
• SMILES string: CC(C)c1cccc(C(C)C)c1N
• InChI: 1S/C12H19N/c1-8(2)10-6-5-7-11(9(3)4)12(10)13/h5-9H,13H2,1-4H3
• InChI key: WKBALTUBRZPIPZ-UHFFFAOYSA-N

Description

General description

2,6-Diisopropylaniline on condensation with triacetylmethane in toluene in the presence of p-toluenesulfonic acid provides 3-[1-(2,6-diisopropylphenylamino)ethylidene]pentane-2,4-dione.[1]

Application

2,6-Diisopropylaniline was used in the preparation of multitopic Schiff-base ligand precursors.[2] It was also used in the preparation of NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene.[3]

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H319,H412
• pcodes: P273 - P305 + P351 + P338
• Hazard Classifications: Aquatic Chronic 3 - Eye Irrit. 2
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 2
• ppe: Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)