MilliporeSigma
All Photos(1)

157910

Sigma-Aldrich

Methyl bromoacetate

97%

Linear Formula:
BrCH2COOCH3
CAS Number:
Molecular Weight:
152.97
Beilstein:
506256
EC Number:
MDL number:
PubChem Substance ID:

Quality Level

assay

97%

form

liquid

refractive index

n20/D 1.458 (lit.)

bp

51-52 °C/15 mmHg (lit.)

density

1.616 g/mL at 25 °C (lit.)

SMILES string

COC(=O)CBr

InChI

1S/C3H5BrO2/c1-6-3(5)2-4/h2H2,1H3

InChI key

YDCHPLOFQATIDS-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Methyl bromoacetate is an α-bromo ester. Reactions of the methyl bromoacetate with conjugate base of (methylmethoxycarbene)pentacarbonylchromium(0) yields alkylated carbene complexes.

Application

Methyl bromoacetate was used in the synthesis of novel coumarins. It was also employed in the synthesis of cis-cyclopropanes.

Packaging

25, 100 g in glass bottle

Pictograms

CorrosionSkull and crossbones

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

147.2 °F

Flash Point(C)

64 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

Enter Lot Number to search for Certificate of Analysis (COA).

Certificate of Origin

Enter Lot Number to search for Certificate of Origin (COO).

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service