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158216

Methyl dichlorophosphate

85%

Synonym(s):

Methyl phosphorodichloridate

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Pack SizeSKUAvailabilityPrice
25 g

Available to ship TODAYfromMILWAUKEE

$173.00

About This Item

Linear Formula:
Cl2P(O)OCH3
CAS Number:
677-24-7
Molecular Weight:
148.91
NACRES:
NA.22
PubChem Substance ID:
24849724
UNSPSC Code:
12352100
EC Number:
211-639-1
MDL number:
MFCD00002068
Assay:
85%

$173.00

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Quality Level

100

assay

85%

refractive index

n20/D 1.436 (lit.)

bp

62-64 °C/15 mmHg (lit.)

density

1.488 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

COP(Cl)(Cl)=O

InChI

1S/CH3Cl2O2P/c1-5-6(2,3)4/h1H3

InChI key

SNVCRNWSNUUGEA-UHFFFAOYSA-N

Application

Methyl dichlorophosphate was used in the synthesis of:
  • 4,6-cyclic phosphate tetrasaccharide[1]
  • 8-(2′′-hydroxyethoxy)adenosine-5′,2′′-phosphate derivative[2]
  • analogs of (R)-1-O-hexadecyl-2-palmitoyl-sn-glycero-3-phosphoethanolamine poly(ethylene glycol)[3]
  • dioxaphosphorino[m,n-x]pyridines compounds

Analysis Note

may contain methyl alcohol as impurity

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1 of 1

This Item
437891E23704D91632
Methyl dichlorophosphate 85%

Sigma-Aldrich

158216

Methyl dichlorophosphate

Dimethyl chlorophosphate 96%

Sigma-Aldrich

437891

Dimethyl chlorophosphate

Ethyl dichlorophosphate 96%

Sigma-Aldrich

E23704

Ethyl dichlorophosphate

Diethyl chlorophosphate 97%

Sigma-Aldrich

D91632

Diethyl chlorophosphate

assay

85%

assay

96%

assay

96%

assay

97%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

refractive index

n20/D 1.436 (lit.)

refractive index

n20/D 1.413 (lit.)

refractive index

n20/D 1.434 (lit.)

refractive index

n20/D 1.416 (lit.)

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

-

density

1.488 g/mL at 25 °C (lit.)

density

1.34 g/mL at 25 °C (lit.)

density

1.373 g/mL at 25 °C (lit.)

density

1.194 g/mL at 25 °C (lit.)

bp

62-64 °C/15 mmHg (lit.)

bp

80 °C/25 mmHg (lit.)

bp

60-65 °C/10 mmHg (lit.)

bp

60 °C/2 mmHg (lit.)

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW1849
MKCK4768
MKCB1610V
MKBG6668V
02724AJ

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T Maruyama et al.
Nucleic acids symposium series, (17)(17), 61-63 (1986-01-01)
Reaction of 8-bromo-2',3'-O-isopropylidene-5'-O-(tetrahydropyran-2-yl) adenosine (Ib) with lithium 2-(tetrahydropyran-2-yloxy) ethoxide, followed by removal of the tetrahydropyran-2-yl groups, afforded 8-(2''-hydroxyethoxy)-2',3'-O-isopropylideneadenosine (II). Successive treatment of II with n-butyllithium and with methyl dichlorophosphate provided the 5',2''-(methyl phosphate) derivative (IIIa and IIIb).
Dominika Turek et al.
Organic & biomolecular chemistry, 4(7), 1236-1241 (2006-03-25)
A spacer-equipped tetrasaccharide, p-aminocyclohexylethyl alpha-l-Colp-(1-->2)-beta-d-Galp-(1-->3)-[alpha-l-Colp-(1-->4)]-beta-D-GlcpNAc, containing a 4,6-cyclic phosphate in the galactose residue, has been synthesised. The structure corresponds to a part of the repeating unit of the capsular (and lipo-) polysaccharide of the endemic bacteria Vibrio cholerae type O139
Thomas L Andresen et al.
Journal of medicinal chemistry, 47(7), 1694-1703 (2004-03-19)
An enzymatically activated liposome-based drug-delivery concept involving masked antitumor ether lipids (AELs) has been investigated. This concept takes advantage of the cytotoxic properties of AEL drugs as well as the membrane permeability enhancing properties of these molecules, which can lead
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Global Trade Item Number

SKUGTIN
158216-25G04061837655173

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