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MilliporeSigma

159549

Sigma-Aldrich

4-(Bromomethyl)benzoic acid

97%

Synonym(s):

α-Bromo-p-toluic acid

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5 G
$52.70
10 G
$99.80
50 G
$340.00

About This Item

Linear Formula:
BrCH2C6H4CO2H
CAS Number:
Molecular Weight:
215.04
Beilstein/REAXYS Number:
1862870
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

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$52.70


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assay

97%

form

solid

mp

224-229 °C (lit.)

functional group

bromo
carboxylic acid

SMILES string

OC(=O)c1ccc(CBr)cc1

InChI

1S/C8H7BrO2/c9-5-6-1-3-7(4-2-6)8(10)11/h1-4H,5H2,(H,10,11)

InChI key

CQQSQBRPAJSTFB-UHFFFAOYSA-N

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1 of 4

This Item
196894270792328901
assay

97%

assay

98%

assay

95%

assay

98%

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

mp

224-229 °C (lit.)

mp

219-220 °C (lit.)

mp

201-202 °C (lit.)

mp

134-138 °C (lit.)

form

solid

form

powder

form

powder

form

-

functional group

bromo

functional group

carboxylic acid, fluoro

functional group

carboxylic acid, chloro

functional group

carboxylic acid, fluoro, nitro

Application

4-(Bromomethyl)benzoic acid was used in the chemical modification of 5,10,15,20-tetra(m-hydroxyphenyl)chlorin (temoporfin), second generation photosensitizer.[1] It was also used in the synthesis of 4-(5-arylidene-2,4-dioxothiazolidin-3-yl) methylbenzoic acids.[2]

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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